Scholarly article on topic 'Fenton-Like Oxidation of Malachite Green Solutions: Kinetic and Thermodynamic Study'

Fenton-Like Oxidation of Malachite Green Solutions: Kinetic and Thermodynamic Study Academic research paper on "Chemical engineering"

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Academic research paper on topic "Fenton-Like Oxidation of Malachite Green Solutions: Kinetic and Thermodynamic Study"

Hindawi Publishing Corporation

Journal of Chemistry

Volume 2013, Article ID 809318, 7 pages

Research Article

Fenton-Like Oxidation of Malachite Green Solutions: Kinetic and Thermodynamic Study

Saeedeh Hashemian

ChemistryDepartment, IslamicAzad University, YazdBranch, P. O. Box89195/155, Yazd, Iran Correspondence should be addressed to Saeedeh Hashemian; Received 25 May 2013; Revised 19 June 2013; Accepted 25 June 2013 Academic Editor: Oleksandr A. Loboda

Copyright © 2013 Saeedeh Hashemian. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Oxidation by Fenton-like (Fe3+/H2O2) reactions is proven to be an economically feasible process for destruction of a variety of hazardous pollutants in wastewater. In this study, the degradation and mineralization of malachite green dye are reported using Fenton-like reaction. The effects of different parameters like pH of the solution, the initial concentrations dye, temperature, and added electrolytes (Cl- and SO4 2-) on the oxidation of the dye were investigated. Optimized condition was determined. The efficiency of 95.5% degradation of MAG after 15 minutes of reaction at pH 3 was obtained. TOC removal indicates partial and insignificant mineralization of malachite green dye. The results of experiments showed that degradation of malachite green dye in Fenton-like oxidation process can be described with a pseudo-second-order kinetic model. The thermodynamic constants of the Fenton oxidation process were evaluated. The results implied that the oxidation process was feasible, spontaneous, and endothermic. The results will be useful for designing the treatment systems of various dye-containing wastewaters.

1. Introduction

Dyes in wastewater are of particular environmental concern since they not only give an undesirable color to the waters but also in some cases are harmful compounds and can originate dangerous by-products through oxidation, hydrolysis, or other chemical reactions taking place in the waste phase. Environmental research has paid special attention to dye compounds because of the extensive environmental contamination arising from dyeing operations. Various attempts have been made for the removal of dyes from water and wastewater. There are several methods applicable for the reclamation of dyeing wastewaters [1, 2]. Commonly applied treatment methods for color removal from dye-contaminated effluents consist of various processes involving biological, physical and chemical decolorization methods. The biological treatment is not a complete solution to the problem due to biological resistance of some dyes [3]. The traditional treatment techniques were applied in wastewaters, such as ozonation [4],membrane [5], oxidation [6,7],photochemical [8], and adsorption [9-13]. Various Fenton processes were used for oxidation of dyes. Homogenous Fenton reaction (Fe2+/H2O2) is one of the most important processes to

generate hydroxyl radicals •OH [14-16]. These processes are involved in the generation of highly reactive radicals (especially hydroxyl radicals) in enough quantity to affect water purification, and their use is justified by the low organic content of the wastewaters to be treated. They have low reaction temperatures and thus require the presence of very active oxidation agents. In particular, the oxidation using Fenton's reagent has proved to be a promising and attractive treatment method for the effective destruction of a large number of hazardous and organic pollutants [17-21].

The Fenton process completely destroys contaminants and breaks them down into harmless compounds, such as carbon dioxide, water, and inorganic salts. However, its applications are limited due to the generation of excessive amounts of ferric hydroxide sludge that requires additional separation process and disposal [22].

Malachite green is classified in the dyestuff industry as a triarylmethane dye. Malachite green (MAG) is usually used as a dye for materials such as silk, leather, and paper. Removal of malachite green by different methods such as oxidation [23], catalytic oxidation [24], electrooxidation [25], and adsorption by agro-industry waste [26], peel [27], and solid agricultural waste [28,29] was studied.

Fenton's reagent is a mixture of ferrous ion and hydrogen peroxide generating hydroxyl radical fOH) in situ according to the following equation:

Fe2+ + H2O2

Fe3+ + OH- + •OH

Fe(III) can catalyze the decomposition of H2O2. The reaction of H2O2 with Fe3+ (the so-called Fenton's-like reagent) goes through the formation of hydroperoxyl radical HO/ [30]:

Fe3+ + H2O2 —> Fe2+ + HO/ + H+ (2)

Fe3+ + HO/ —> Fe2+ + H+ + O2 (3)

Fe2+ + •OH — Fe3+ + -OH (4)

•OH + H2O2 — > HO/ + H2O (5)

Fe2+ + HO/ — Fe3+ + HO2- (6)

•OH + HO" ' H2O2 (7)

The specific objectives of this study are the investigation of removal efficiencies of malachite green (MAG) by Fenton-like process. Important variables such as oxidation time, effect of pH, dosages of H2O2, and ferrous ions were examined. The kinetics and thermodynamic of process also were determined.

2. Experimental

2.1. Material and Methods. The basic dye, MAG, has molecular formula C23H25ClN2 and molar mass 364.911 g/mol with Amax 620 nm and was used as received without further purification to prepare simulated wastewater. 5.0 x 10-3 stock solution of MAG was prepared, and working solutions are prepared by the dilution. Experimental solutions of the desired concentration were obtained by successive dilutions. The chemical structure of malachite green (4-[(4-dimethylaminophenyl)phenyl-methyl]-N,N-dimethylaniline) is shown in Figure 1.

All the reagents used in the experiments were in analytical grade (Merck) and were used without further purification. All the experiments were conducted at room temperature. The dye oxidation was achieved by Fenton-like reagent which was composed of a mixture of Fe2(SO4)3-7H2O and H2O2 (30%). The necessary quantities of Fe3+ and H2O2 were added simultaneously in the dye solution. All experiments were conducted in a 500 mL thermostated batch glass reactor equipped with the magnetic stirrer. The kinetics of oxidation was followed by taking samples at regular time interval.

The residual concentration of the MAG in the solution at different times of sampling was determined. The residual concentration of the dye was deducted from the calibration curves which were produced at wavelength corresponding to the maximum of absorbance (620 nm) on an UV-visible spectrophotometer apparatus (Shimadzu 160 A). The cells used were in quartz 1 cm thick. The discoloration efficiency

Figure 1: Chemical structure of malachite green (MAG).

of the dye (X) with respect to its initial concentration is calculated as

%X = ([MAG]0 - [MAG] /[MAG]0) x 100,

where [MAG]0 and [MAG] are the initial and appropriate concentrations of dye at any reaction time i, respectively.

3. Results and Discussion

3.1. Effect ofpH on Decolorization. pH has a major effect on the efficiency of MAG treatment. The oxidation was done for 120 min under controlled pH condition with constant dose of Fe3+ (1.0 x 10-4 M) and H2O2 (5 x 10-2 M). The effect of pH on the removal of malachite green using 50mgL-1 of dye was studied. The oxidation of MAG as a function of pH is shown in Figure 2. It is evident that change in the pH of the solution to Fenton-like value of 3 leads to increases in the extent of MAG oxidation. It is apparent from that extent of decolorization decreases with increase in pH, and at pH 3.0 almost >95% color removal was observed. Therefore, the results demonstrate that the pH value for the most effective oxidation of MAG is approximately 3. The decrease in oxidation rate at pH > 3 could be explained by the formation of Fe(OH)3, which has lower catalytic activity in the decomposition of H2O2 [30]. The low activity detected for high pH has been reported, and the results closely agreed with those in the literature [19, 30-32].

3.2. Effect ofFe3+ Ferrous Dosage. The concentration of Fe3+ is one of the critical parameters in Fenton processes. In the present study, the influence of different iron concentrations (Fe3+ = 1.0 x 10-6-1.0 x 10-3 M) expressed as MAG removal is illustrated in Figure 3. The concentration of hydrogen peroxide is fixed as 0.05 M, and MAG concentration is 3.0 x 10-5 M. It can be seen from results that MAG degradation increased with increasing Fe+ concentrations. This is due to the fact that Fe+3 plays a very important role in the decompositions of H2O2 to generate the ^OH in the Fenton process. The lower degradation capacity of Fe3+ at small concentration is probably due to the lowest ^OH radicals producing a variable for oxidation [16, 19], for higher concentration of Fe+3 oxidation of dye will decrease. This can be explained by

100 -,

Ж 80 -

—ж—ж ж ж ж ж ж-^-^к ---

Time (min)

-♦- pH 3 -Х- pH 7 -И- pH 2

pH 9 pH 5 pH 10

Figure 2: Effect of pH on the discoloration efficiency for Fenton-like oxidation process, ([Fe3+]=1.0 x 10-4 M, [H202]=5.0x 10-2 M, [MAG] = 3.0 x 10-5 M).

■ä 40 -

Time (min)

5 x 10 5 x 10-

Figure 4: Effect of H2O2

1.0 x 10 2 -X- 1 x 10-1

concentration on the discoloration efficiency for Fenton-like oxidation process ([MAG] =3.0 x 10-5 M, [Fe+3] = 1.0 x 10-4]).

10 10-

Time (min) 10-4 -Х- 10-6

Figure 3: Effect of Fe3+ concentration on the discoloration efficiency for Fenton-like oxidation process, ([H202] = 5.0 x 10-2, [MAG] =3.0 x 10-5 M).

the fact that, when the concentrations of Fe3+ are high, can react with the HO/ and finally reduce consumed the very reactive • OH radical according to (3).

3.3. Effect of H2O2 Concentration. H202 plays the role of an oxidizing agent in this process. The selection of an optimal H202 concentration for the decolorization of MAG is important from practical point of view due to the cost of H2O2 [33].

Oxidation of dyes by Fenton and Fenton-like process is carried out by •OH radicals that are directly produced from

the reaction between H2O2,

Fe +, and Fe To determine

the concentration of H2O2 giving the maximum MAG discoloration efficiency, experiments were conducted, and results detained are represented in Figure 4.Thediscoloration efficiency according to time for different concentrations of

H2O2 shows that the dye degradation yield increases with increasing concentration of H2O2. For the oxidation process, the addition of H2O2 from 5.0 x 10-3-1.0 x 10-1 M increases the decolorization from 68 to 95% at 10min. The increase in the decolorization is due to the increase in hydroxyl radical concentration by addition of H2O2 [17]. However at higher H2O2 concentration, efficiency of dye removal showed no significant efficiency, which is due to recombination of hydroxyl radicals, and scavenging the OH radicals will occur, which can be expressed by (2), (5), and (6).

3.4. Effect of Relation [Fe3+]/[H202]. The ables affecting the rate of a Fenton-like reaction are the molar concentrations of the oxidant (H2O2) and catalyst (Fe3+), particularly the Fe +: H2O2 molar ratio. Therefore, color removal as a function of the initial molar ratio of Fe3+/H2O2 was investigated. The different ratios of [Fe3+]/[H2O2] 1-400 are reported from the literature. The experimental results showed that the optimum Fe3+: H2O2 molar ratio for the removal of MAG was 1:50 [19, 34]. The reaction of Fe3+ with H2O2 leads to the formation of Fe2+ ions, which can further react with H2O2 to produce OH radical. Therefore, a low Fe3+ concentration decreases MAG degradation. MAG removal actually ceased when the Fe3+: H2O2 molar ratio increased from 1: 50to 1: 500 for 1 mM Fe3+, indicating that H2O2 was overdosed when its concentration rose tenfold. In the presence of 50 mM of H2O2, the ionic liquid is probably eliminated solely by the reaction with •OH, but at 500 mM; as it is expected, most of the H2O2 dosage applied was consumed in the first stage of the fast reaction. The oxidation of ionic liquids was done not only by reaction with •OH radicals but also by other radical species generated in vigorous Fe+ /H2O2 reactions such FeO3+ [35] and Fe3+HO22+ [30] which then decrease.

3.5. Effect of Dye Concentration. The efficiency of the Fenton-like process as a function of initial concentration of dye was

evaluated. Figure 5 shows the changes of MAG concentration with the reaction time. The results indicated that decoloriza-tion efficiency increased when the initial dye concentration increased. Concentration plays a very important role in reactions according to the collision theory of chemical reactions. Two reactants were in a closed container. All the molecules contained within are colliding constantly. By increasing the concentration of one or more reactants, the frequency of collisions between reactant molecules is increased, and the frequencyofeffectivecollisionsthatcausesareaction to occur will also be high. The lifetime of hydroxyl radicals is very short (only a few nanoseconds), and they can only react where they are formed; therefore, as increasing the quantity of dye molecules per volume unit logically enhances the probability of collision between organic matter and oxidizing species, leading to an increase in the decolorization efficiency [36].

3.6. Effect of Temperature. The influence of reaction temperature on the decolorization efficiency of MAG was investigated by varying temperature from 20°C to 70°C. Temperature is critical to the reaction rate, product yield, and distribution. The result is illustrated in Figure 6. It can be seen that raising the temperature has a positive impact on the decolorization of MAG. The decolorization efficiency within 10 min reaction increased from 78% to 95% as the different temperatures. This is due to the fact that higher temperature increased the reaction rate between hydrogen peroxide and the catalyst, thus increasing the rate of generation of oxidizing species such as •OH radical or high-valence iron species [34]. In addition, a higher temperature can provide more energy for the reactant molecules to overcome reaction activation energy [37]. Although the decolorization efficiency for T = 30°C is lower than those obtained at T = 40°C, the values of dyes removal achieved at 30°C might be considered satisfactory. At higher temperature, the efficiency of MAG oxidation decreases. This phenomenon may be due to the decomposition of H2O2 at the relatively high temperatures (9). This is consistent with results found in the literature [38]:

100 -,

g 80 -

« 50 c

■2 40 -I

S 30 -

Q 2010 -

1 x 10

5 x 10-

1 x 10

Time (min) -•- 1 x 103 x 10-

Figure 5: Effect of MAG concentration on the discoloration efficiency for Fenton-like oxidation process.

Q 50 -

30° C 40° C 70° C

Time (min)

50° C -A- 20° C - - 60°C

H2O + O2

3.7. Mineralization Study. The complete mineralization of 1 mol MAG dye molecule implies the formation of the equivalent amount (23 moles) of CO2 at the end of the treatment. However, the depletion in TOC (shown in Figure 7) clearly indicates that the reaction does not go to completion. Extent of mineralization of the dye by Fenton-like process can be evaluated by measuring Total Organic Carbon (TOC). To determine the change in the TOC of reaction medium, initial TOC (pure dye solution) and the TOC of a sample at different intervals during the reaction were measured. TOC reduction was determined as follows:


1 - TOCt TOCo

X 100,

where TOCt and TOC0

(mg L- ) are values at time (t) and at time (0), respectively. 70% TOC reduction is achieved for MAG dye in 30 min. In fact, after 30 min of reaction,

Figure 6: Effect of temperature on the discoloration efficiency for Fenton-like oxidation process.

about 70% of the initial organic carbon had been transformed into CO2, which implied the existence of other organic compounds in the solution and the partial mineralization of dyes [39,40].

3.8. Effect of CT and SO42- on Fenton Effectiveness. Cl-and SO42- are common coexisting anions with dyes in wastewater; therefore, the effect of Cl- and SO4 - ions on MAG removal by Fenton-like process was investigated. It was found that the presence of Cl- at the concentration range of 0-0.1 mol L-1 did not have a significant effect on removing MAG. The effect of SO42- on the removal of MAG was significant at the concentration range of 0-0.1 mol L-1. The removal of MAG decreased at a concentration of 0.02 mol L-1

о н 20

50 100

Time (min)

Figure 7: TOC removal for MAG dye by Fenton-like oxidation process.

of SO42 . The removal of MAG decreased to 45% for concentration of 0.02 mol L-1 of SO42-.

3.9. Kinetic of Fenton Reaction. The general elementary rate law for reaction of a target organic compound (MAG) can be written as follows:

- ^HO^OH^RH + ^oxi^oxiCrh,

where oxi represents oxidants other than •OH that may be present, such as ferryl, hydroxyl radical which is usually regarded as the sole or most important reactive species. Then

- ^HO^OH ^MAG-

And, by integration, the rate law of first-order reaction can be written as follows:

ln Cmag - ln C(MAG)0 ^app

where CMAG and C(MAG)0 are initial concentration of MAG and concentration of MAG at any time. A plot of ln CMAG versus time generated a straight line with a negative slope. The slope of this line corresponds to the apparent rate constant value for the degradation of the organic target compound. In our case, we follow the rate of decolourization of the MAG dye. Consequently, (13) was converted to


Figure 8 shows the plot of first-order Fenton reaction. Rate law of the second-order reaction can be written as follows:


The plot of 1/[C] against k shows the rate constant of second-order Fenton reaction (Figure 9). The results from R of Figures 8 and 9 show that the kinetic of Fenton-like reaction for degradation of MAG was second-order reaction

-2.5 -

y = -0.017x- 2.2362 R2 = 0.9439

-3.5 -

-4.5 J

0 20 40 60

100 120

Time (min)

Figure 8: Pseudo-first-order model for Fenton-like oxidation of MAG.

70 60 50 40 30 20 10 0

y = 0.4613x + 2.616 R2 = 0.9951

Time (min)

Figure 9: Pseudo-second-order model for Fenton-like oxidation of MAG.

3.10. Thermodynamic of Fenton Reaction. Thermodynamic parameters including Gibbs free energy AG°, standard enthalpy AH°, and standard entropy AS° are the parameters to better understand the temperature effect on degradation of dye which was studied. Gibbs free energy AG° by using equilibrium constant is calculated:

- -ДГ ln

value is calculated from the following formula:

CAe is amount of degradation dye at equilibrium and CSe equilibrium concentration of dye at the solution.

Standard enthalpy AH° and standard entropy AS° are as van't Hoff equation:

, ^ -AH" AS°

ln --+--

In this equation R is the gas constant equal to the public (8.314 J mol-1 k-1). The amounts of degradation dye at equilibrium at different temperatures 25-55"C have been examined to obtain thermodynamic parameters for Fenton-like reaction of MAG. AH° and AS° were calculated as the slope and intercept of van't Hoff plots of ln versus

Table 1: Thermodynamic parameters for Fenton oxidation of MAG ([MAG] = 3.0 x 10-5 M, [Fe3+] = 1.0 x 10-4 M, [H2O2] = 5.0 x 10-2 M).

AS" AH° AG" Kc T (K)

(Jmol-1k- 1) (Jmol-1) (KJmol-1)

-3.255 3.80 293 Fenton

43.2823 9.610 -3.408 3.870 303

-4.213 4.80 323 oxidation

-5.680 7.33 333

1/T. The results of thermodynamic parameters are given in Table 1. As observed in Table 1, negative value of AG° at different temperatures shows the oxidation process to be spontaneous. The AH° positive value indicates that the uptake is endothermic [42].

4. Conclusion

The results of Fenton-like oxidation process of MAG showed the following.

(1) The optimal parameters for Fenton-like process are [MAG] = 3 x 10-5 M, [Fe3+] = 1.0 x 10-3 M,

[H2O2] = 5 x 10-2 M, pH = 3.

(2) Fenton-like process not only completes decoloriza-tion of MAG dye (95%) but also mineralizes it (70%).

(3) The oxidation process of MAG follows pseudo-second-order kinetic model.

(4) The negative values of AG° and positive value of AH° obtained indicated that the MAG dye oxidation by Fenton reaction processes is spontaneous and endothermic.

(5) The overall equation of MAG degradation and production of carbon dioxide and nitrate ion is as follows:

C23H25CW2 + 52H2O

23 CO2 + 129H+

+ 2NO3 + Cl + 126e


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