Scholarly article on topic 'Theoretical methods for understanding advanced magnetic materials: The case of frustrated thin films'

Theoretical methods for understanding advanced magnetic materials: The case of frustrated thin films Academic research paper on "Physical sciences"

CC BY
0
0
Share paper
OECD Field of science
Keywords
{"Theory of magnetism" / "Magnetic thin films" / "Surface spin waves" / "Frustrated spin systems" / "Magnetic materials" / "Phase transition" / "Monte Carlo simulation" / "Statistical physics"}

Abstract of research paper on Physical sciences, author of scientific article — H.T. Diep

Abstract Materials science has been intensively developed during the last 30 years. This is due, on the one hand, to an increasing demand of new materials for new applications and, on the other hand, to technological progress which allows for the synthesis of materials of desired characteristics and to investigate their properties with sophisticated experimental apparatus. Among these advanced materials, magnetic materials at nanometric scale such as ultra thin films or ultra fine aggregates are no doubt among the most important for electronic devices. In this review, we show advanced theoretical methods and solved examples that help understand microscopic mechanisms leading to experimental observations in magnetic thin films. Attention is paid to the case of magnetically frustrated systems in which two or more magnetic interactions are present and competing. The interplay between spin frustration and surface effects is the origin of spectacular phenomena which often occur at boundaries of phases with different symmetries: reentrance, disorder lines, coexistence of order and disorder at equilibrium. These phenomena are shown and explained using of some exact methods, the Green's function and Monte Carlo simulation. We show in particular how to calculate surface spin-wave modes, surface magnetization, surface reorientation transition and spin transport.

Academic research paper on topic "Theoretical methods for understanding advanced magnetic materials: The case of frustrated thin films"

Contents lists available at ScienceDirect

Journal of Science: Advanced Materials and Devices

journal homepage: www.elsevier.com/locate/jsamd

Review article

Theoretical methods for understanding advanced magnetic materials: The case of frustrated thin films

CrossMark

H.T. Diep

Laboratoire de Physique Théorique et Modélisation, Université de Cergy-Pontoise, CNRS, UMR 8089, 2, Avenue Adolphe Chauvin, 95302 Cergy-Pontoise Cedex, France

ARTICLE INFO

Article history: Received 3 April 2016 Accepted 16 April 2016 Available online 22 April 2016

Keywords:

Theory of magnetism Magnetic thin films Surface spin waves Frustrated spin systems Magnetic materials Phase transition Monte Carlo simulation Statistical physics

ABSTRACT

Materials science has been intensively developed during the last 30 years. This is due, on the one hand, to an increasing demand of new materials for new applications and, on the other hand, to technological progress which allows for the synthesis of materials of desired characteristics and to investigate their properties with sophisticated experimental apparatus. Among these advanced materials, magnetic materials at nanometric scale such as ultra thin films or ultra fine aggregates are no doubt among the most important for electronic devices.

In this review, we show advanced theoretical methods and solved examples that help understand microscopic mechanisms leading to experimental observations in magnetic thin films. Attention is paid to the case of magnetically frustrated systems in which two or more magnetic interactions are present and competing. The interplay between spin frustration and surface effects is the origin of spectacular phenomena which often occur at boundaries of phases with different symmetries: reentrance, disorder lines, coexistence of order and disorder at equilibrium. These phenomena are shown and explained using of some exact methods, the Green's function and Monte Carlo simulation. We show in particular how to calculate surface spin-wave modes, surface magnetization, surface reorientation transition and spin transport.

© 2016 Publishing services by Elsevier B.V. on behalf of Vietnam National University, Hanoi. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).

1. Introduction

Material science has made a rapid and spectacular progress during the last 30 years, thanks to the advance of experimental investigation methods and a strong desire of scientific community to search for new and high-performance materials for new applications. In parallel to this intensive development, many efforts have been devoted to understanding theoretically microscopic mechanisms at the origin of the properties of new materials. Each kind of material needs specific theoretical methods in spite of the fact that there is a large number of common basic principles that govern main properties of each material family.

In this paper, we confine our attention to the case of magnetic thin films. We would like to show basic physical principles that help us understand their general properties. The main purpose of the paper is not to present technical details of each of them, but rather to show what can be understood using each of them. For technical

E-mail address: diep@u-cergy.fr.

Peer review under responsibility of Vietnam National University, Hanoi.

details of a particular method, the reader is referred to numerous references given in the paper. For demonstration purpose, we shall use magnetically frustrated thin films throughout the paper. These systems combine two difficult subjects: frustrated spin systems and surface physics. Frustrated spin systems have been subject of intensive studies during the last 30 years [1]. Thanks to these efforts many points have been well understood in spite of the fact that there remains a large number of issues which are in debate. As seen below, frustrated spin systems contain many exotic properties such as high ground-state degeneracy, new symmetries, successive phase transitions, reentrant phase and disorder lines. Frustrated spin systems serve as ideal testing grounds for theories and approximations. On the other hand, during the same period surface physics has also been widely investigated both experimentally and theoretically. Thanks to technological progress, films and surfaces with desired properties could be fabricated and characterized with precision. As a consequence, one has seen over the years numerous technological applications of thin films, coupled thin films and super-lattices, in various domains such as magnetic sensors, magnetic recording and data storage. One of the spectacular effects is

http://dx.doi.org/10.1016/j.jsamd.2016.04.009

2468-2179/© 2016 Publishing services by Elsevier B.V. on behalf of Vietnam National University, Hanoi. This is an open access article under the CC BY license (http:// creativecommons.org/licenses/by/4.0/).

the colossal magnetoresistance [2,3] which yields very interesting transport properties. The search for new effects with new mechanisms in other kinds of materials continues intensively nowadays as never before.

Section 2 is devoted to the presentation of the main theoretical background and concepts to understand frustrated spin systems and surface effects in magnetic materials. Needless to say, one cannot cover all recent developments in magnetic materials but an effort is made to outline the most important ones in our point of view. Section 3 is devoted to a few examples to illustrate striking effects due to the frustration and to the presence of a surface. Concluding remarks are given in Section 4.

2. Background

2.1. Theory of phase transition

Many materials exhibit a phase transition. There are several kinds of transition, each transition is driven by the change of a physical parameter such as pressure, applied field, temperature (T), ... The most popular and most studied transition is no doubt the one corresponding to the passage from a disordered phase to an ordered phase at the so-called magnetic ordering temperature or Curie temperature Tc. The transition is accompanied by a symmetry breaking. In general when the symmetry of one phase is a subgroup of the other phase the transition is continuous, namely the first derivatives of the free energy such as internal energy and magnetization are continuous functions of T. The second derivatives such as specific heat and susceptibility, on the other hand, diverge at Tc. The correlation length is infinite at Tc. When the symmetry of one phase is not a symmetry subgroup of the other, the transition is in general of first order: the first derivatives of the free energy are discontinuous at Tc. At the transition, the correlation length is finite and often there is a coexistence of the two phases. For continuous transitions, also called second-order transition, the nature of the transition is characterized by a set of critical exponents which defines its "universality class". Transitions in different systems may belong to the same universality class.

Why is the study of a phase transition interesting? As the theory shows it, the characteristics of a transition are intimately connected to microscopic interactions between particles in the system.

The theory of phase transitions and critical phenomena has been intensively developed by Landau and co-workers since the 50's in the framework of the mean-field theory. Microscopic concepts have been introduced only in the early 70's with the renormalization group [4—6]. We have since then a clear picture of the transition mechanism and a clear identification of principal ingredients which determine the nature of the phase transition. In fact, there is a small number of them such as the space dimension, the nature of interaction and the symmetry of the order parameter.

2.2. Frustrated spin systems

A spin is said "frustrated" when it cannot fully satisfy all the interactions with its neighbors. Let us take a triangle with an an-tiferromagnetic interactionJ(<0) between two sites: we see that we cannot arrange three Ising spins (±1) to satisfy all three bonds. Among them, one spin satisfies one neighbor but not the other. It is frustrated. Note that any of the three spins can be in this situation. There are thus three equivalent configurations and three reverse configurations, making 6 the number of "degenerate states". If we put XY spins on such a triangle, the configuration with a minimum energy is the so-called "120-degree structure" where the two neighboring spins make a 120° angle. In this case, each interaction bond has an energy equal to J|cos(2p/3) = — J|/2, namely half of

the full interaction: the frustration is equally shared by three spins, unlike the Ising case. Note that if we go from one spin to the neighboring spin in the trigonometric sense we can choose cos(2p/ 3) or — cos(2p/3) for the turn angle: there is thus a two-fold degeneracy in the XY spin case. The left and right turn angles are called left and right chiralities. In an antiferromagnetic triangular lattice, one can construct the spin configuration from triangle to triangle. The frustration in lattices with triangular plaquettes as unit such as in face-centered cubic and hexagonal-close-packed lattices is called "geometry frustration". Another category of frustration is when there is a competition between different kinds of incompatible interactions which results in a situation where no interaction is fully satisfied. We take for example a square with three ferromagnetic bonds J( > 0) and one antiferromagnetic bond —J, we see that we cannot "fully" satisfy all bonds with Ising or XY spins put on the corners.

Frustrated spin systems are therefore very unstable systems with often very high ground-state degeneracy. In addition, novel symmetries can be induced such as the two-fold chirality seen above. Breaking this symmetry results in an Ising-like transition in a system of XY spins [7,8]. As will be seen in some examples below, the frustration is the origin of many spectacular effects such as non collinear ground-state configurations, coexistence of order and disorder, reentrance, disorder lines, multiple phase transitions, etc.

2.3. Surface magnetism

In thin films the lateral sizes are supposed to be infinite while the thickness is composed of a few dozens of atomic layers. Spins at the two surfaces of a film lack a number of neighbors and as a consequence surfaces have physical properties different from the bulk. Of course, the difference is more pronounced if, in addition to the lack of neighbors, there are deviations of bulk parameters such as exchange interaction, spin-orbit coupling and magnetic anisot-ropy, and the presence of surface defects and impurities. Such changes at the surface can lead to surface phase transition separated from the bulk transition, and surface reconstruction, namely change in lattice structure, lattice constant [9], magnetic ordering, ... at the surface [10—12].

Thin films of different materials, different geometries, different lattice structures, different thicknesses ... when coupled give surprising results such as colossal magnetoresistance [2,3]. Microscopic mechanisms leading to these striking effects are multiple. Investigations on new artificial architectures for new applications are more and more intensive today. In the following section, we will give some basic microscopic mechanisms based on elementary excitations due to the film surface which allows for understanding macroscopic behaviors of physical quantities such as surface magnetization, surface phase transition and transition temperature.

2.4. Methods

To study properties of materials one uses various theories in condensed matter physics constructed from quantum mechanics and statistical physics [13,14]. Depending on the purpose of the investigation, we can choose many standard methods at hand (see details in Refs. [15,16]):

(i) For a quick obtention of a phase diagram in the space of physical parameters such as temperature, interaction strengths,... one can use a mean-field theory if the system is simple with no frustration, no disorder, ... Results are reasonable in three dimensions, though critical properties cannot be correctly obtained

(ii) For the nature of phase transitions and their criticality, the renormalization group [4—6] is no doubt the best tool. However for complicated systems such as frustrated systems, films and dots, this method is not easy to use

(iii) For low-dimensional systems with discrete spin models, exact methods can be used

(iv) For elementary excitations such as spin waves, one can use the classical or quantum spin-wave theory to get the spin-wave spectrum. The advantage of the spin-wave theory is that one can keep track of the microscopic effect of a given parameter on macroscopic properties of a magnetic system at low temperatures with a correct precision

(v) For quantum magnetic systems, the Green's function method allows one to calculate at ease the spin-wave spectrum, quantum fluctuations and thermodynamic properties up to rather high temperatures in magnetically ordered materials. This method can be used for collinear spin states and non collinear (or canted) spin configurations as seen below

(vi) For all systems, in particular for complicated systems where analytical methods cannot be easily applied, Monte Carlo simulations can be used to calculate numerous physical properties, specially in the domain of phase transitions and critical phenomena as well as in the spin transport as seen below.

In the next section, we will show some of these methods and how they are practically applied to study various properties of thin films.

3. Frustrated thin films

3.1. Exactly solved two-dimensional models

Why are exactly solved models interesting? There are several reasons to study such models:

• Many hidden properties of a model cannot be revealed without exact mathematical demonstration

• We do not know of any real material which corresponds to an exactly solved model, but we know that real materials should bear physical features which are not far from properties described in some exactly solved models if similar interactions are thought to exist in these materials.

• Macroscopic effects observed in experiments cannot always allow us to find their origins if we do not already have some theoretical pictures provided by exact solutions in mind.

To date, only systems of discrete spins in one and two dimensions (2D) with short-range interactions can be exactly solved. Discrete spin models include Ising spin, q-state Potts models and some Potts clock-models. The reader is referred to the book by Baxter [17] for principal exactly solved models. In general, one-dimensional (ID) models with short-range interaction do not have a phase transition at a finite temperature. If infinite-range interactions are taken into account, then they have, though not exactly solved, a transition of second or first order depending on the decaying power of the interaction [18—21 ]. In 2D, most systems of discrete spins have a transition at a finite temperature. The most famous model is the 2D Ising model with the Onsager's solution [22].

In this paper, we are also interested in frustrated 2D systems because thin films in a sense are quasi two-dimensional. We have exactly solved a number of frustrated Ising models such as the Kagome lattice [23], the generalized Kagome lattice [24], the

generalized honeycomb lattice [25] and various dilute centered square lattices [26—28].

For illustration, let us show the case of a Kagomee lattice with nearest-neighbor (NN) and next-nearest neighbor (NNN) interactions. As seen below this Kagome model possesses all interesting properties of the other frustrated models mentioned above.

In general, 2D Ising models without crossing interactions can be mapped onto the 16-vertex model or the 32-vertex model which satisfy the free-fermion condition automatically as shown below with an Ising model defined on a Kagomee lattice with interactions between NN and between NNN, J1 and J2, respectively, as shown in Fig. 1.

We consider the following Hamiltonian

(f) (if)

where si = ±1 and the first and second sums run over the spin pairs connected by single and double bonds, respectively. Note that the Kagomee original model, with antiferromagnetic J1 and without J2 interaction, has been exactly solved a long time ago showing no phase transition at finite temperatures [29].

The ground state (GS) of this model can be easily determined by an energy minimization. It is shown in Fig. 2 where one sees that only in zone I the GS is ferromagnetic. In other zones the central spin is undetermined because it has two up and two down neighbors, making its interaction energy zero: it is therefore free to flip. The GS spin configurations in these zones are thus "partially disordered". Around the line J2/J1 = -1 separating zone I and zone IV we will show below that many interesting effects occur when T increases from zero.

The partition function is written as

Z = ^ jjexp[/<i (0105 + 02S5 + S3S5 + S4S5 + 0102 + S3S4)

+ <2(0104 + 03 02)]

where K12 = J1t2/kBT and where the sum is performed over all spin configurations and the product is taken over all elementary cells of the lattice. To solve this model, we first decimate the central spin of each elementary cell of the lattice and obtain a checkerboard Ising model with multi-spin interactions (see Fig. 3).

The Boltzmann weight of each shaded square is given by

4 1 V1/ / 5\ 3 J 2

Fig. 1. Kagome lattice. Interactions between nearest neighbors and between next-nearest neighbors, and J2, are shown by single and double bonds, respectively. The lattice sites in a cell are numbered for decimation demonstration.

II J2 I + - + +

Fig. 2. Ground state of the Kagome lattice in the space (J1J2). The spin configuration is indicated in each of the four zones I, II, III and IV: + for up spins, - for down spins, x for undetermined spins (free spins). The diagonal line separating zones I and IV is given by J2/J1 = -1.

W(ffi, 02, S3, S4) = 2cosh(Ki (si + S2 + S3 + S4))exp[K2(ffiS4

+ 0203)+Ki(0i02 + S3S4)]

The partition function of this checkerboard Ising model is thus Z = Xn W(Si, S2, S3, S4) (4)

where the sum is performed over all spin configurations and the product is taken over all the shaded squares of the lattice.

To map this model onto the 16-vertex model, we need to introduce another square lattice where each site is placed at the center of each shaded square of the checkerboard lattice, as shown in Fig. 4.

At each bond of this lattice we associate an arrow pointing out of the site if the Ising spin that is traversed by this bond is equal to +1, and pointing into the site if the Ising spin is equal to — 1, as it is shown in Fig. 5. In this way, we have a 16-vertex model on the associated square lattice [17]. The Boltzmann weights of this vertex model are expressed in terms of the Boltzmann weights of the checkerboard Ising model, as follows

V ✓ \

Fig. 4. The checkerboard lattice and the associated square lattice with their bonds indicated by dashed lines.

«1 = «2 = 2e~2l<2+2IK «3 = «4 = 2e2<2"2Kl «5 = «6 = 2e"2K2"2Kl «7 = «8 = 2e2«2+2«1cosh(4I<1 )

«9 = «10 = «11 = «12 = «13 = «14 = «15 = «16 = 2cosh(2I<i)

Generally, a vertex model is soluble if the vertex weights satisfy the free-fermion conditions so that the partition function is reducible to the S matrix of a many-fermion system [30]. In the present problem the free-fermion conditions are the following

«1 = «2, «3 = «4 «5 = «6, «7 = «8

«9 = «10 = «11 = «12 (7)

«13 = «14 = «15 = «16

«1«3 + «5«7 — «9 «11 — «13«15 = 0

«1 = W (—, —, +, +) «5 = W (—, +, —, +)

«2 = W (+, +, —, —) «6 = W (+, —, +, —)

«3 = W ( —, +, +, —) «7 = W (+, +, +, +)

«4 = W (+, —, —, +) «8 = W ( —, —, —, —)

«9 = W (—, +, +, +) «13 = W (+, —, +, +)

«10 = W( + , —, —, —) «14 = W ( —, +, —, —)

«11 = W( + , +, —, +) «15 = W (+, +, +, —)

«12 = W( —, —, +, —) «16 = W ( —, —, —, +) Taking Eq. (3) into account, we obtain

• >-t 9

• jM t-< M wk

As can be easily verified, Eq. (7) are identically satisfied by the Boltzmann weights Eq. (6), for arbitrary values of K1 and K2. Using Eq. (6) for the 16-vertex model and calculating the free energy of the model [23,17] we obtain the critical condition for this system

+ ifL-

\/ y'\

m — —

+ + ^-^ -

+ *-* +

+ +■

-»+ + + -

\- \ /' A ►- - ;- \ y A - - ;- \ y A t-i \ y ;-»

Fig. 3. Checkerboard lattice. Each shaded square is associated with the Boltzmann weight W(S1,S2,S3,S4), given in the text.

Fig. 5. The relation between spin configurations and arrow configurations of the associated vertex model.

2 [exp(2K1 + 2K2)cosh(4K1) + exp( - 2K1 - 2K2)] + cosh(2K1 - 2K2) + 2cosh(2K1) = 2max ji [exp(2K1 + 2K2)cosh(4K1) + exp( - 2K1 - 2K2)]; cosh(2K2 - 2K1); cosh(2K1)|

This equation has up to four critical lines depending on the values of J1 and J2. For the whole phase diagram, the reader is referred to Ref. [23]. We show in Fig. 6 only the small region ofJ2/J1 in the phase diagram which has two striking phenomena: the reentrant paramagnetic phase and a disorder line.

The reentrant phase is defined as a paramagnetic phase which is located between two ordered phases on the temperature axis as seen in the region -1 <J2/J1 < -0.91: if we take for instance J2/ J1 = -0.94 and we go up on the temperature axis, we will pass through the ferromagnetic phase F, enter the "reentrant" paramagnetic phase, cross the disorder line, enter the partial disordered phase X where the central spins are free, and finally enter the paramagnetic phase P [23]. The reentrant paramagnetic phase takes place thus between a low-T ferromagnetic phase and a partially disordered phase.

Note that in phase X, all central spins denoted by the number 5 in Fig. 1 are free to flip at all T while other spins are ordered up to the transition at Tc. This result shows an example where order and disorder coexists in an equilibrium state.

It is important to note that though we get the exact solution for the critical surface, namely the exact location of the phase transition temperature in the space of parameters as shown in Fig. 6, we do not have the exact expression of the magnetization as a function of temperature. To verify the coexistence of order and disorder mentioned above we have to recourse to Monte Carlo simulations. This is easily done and the results for the order parameters and the susceptibility of one of them are shown in Fig. 7 for phases F and X at J2/J1 = -0.94. As seen, the F phase disappears at T1 = 0.47 and phase IV (defined in Fig. 2) sets in at T2 =0.50 and disappears for T> 1.14. Tis measured in the unit of J1/kB. The paramagnetic region between T1 and T2 is the reentrant phase. Note that the disorder line discussed below cannot be seen by Monte Carlo simulations.

Let us now give the equation of the disorder line shown in Fig. 6:

„4K2

2( e4K + 1) e8K1 + 3

- 1.0 a

Fig. 6. Phase diagram of the Kagome lattice with NNN interaction in the region Ji > 0 of the space (a = J2/J1,T). T is measured in the unit of J1/kB. Solid lines are critical lines, dashed line is the disorder line. P, F and X stand for paramagnetic, ferromagnetic and partially disordered phases, respectively. The inset shows schematically enlarged region of the endpoint.

Usually, one defines each point on the disorder line as the temperature where there is an effective reduction of dimensionality in such a way that physical quantities become simplified spectacularly. Along the disorder line, the partition function is zero-dimensional and the correlation functions behave as in one dimension (dimension reduction). The disorder line is very important in understanding the reentrance phenomenon. This type of line is necessary for the change of ordering from the high-T ordered phase to the low-T one. In the narrow reentrant paramagnetic region, pre-ordering fluctuations with different symmetries exist near each critical line. Therefore the correlation functions change their behavior when crossing the "dividing line" as the temperature is varied in the reentrant paramagnetic region. On this dividing line, or disorder line, the system "forgets" one dimension in order to adjust itself to the symmetry of the other side. As a consequence of the change of symmetries there exist spins for which the two-point correlation function (between NN spins) has different signs, near the two critical lines, in the reentrant paramagnetic region. Hence it is reasonable to expect that it has to vanish at a disorder temperature TD. This point can be considered as a non-critical transition point which separates two different paramagnetic phases. The two-point correlation function defined above may be thought of as a non-local "disorder parameter". This particular point is just the one which has been called a disorder point by Stephenson [31] in analyzing the behavior of correlation functions for systems with competing interactions. Other models we solved have several disorder lines with dimension reduction [25,26] except the case of the centered square lattice where there is a disorder line without dimension reduction [27].

We believe that results of the exactly solved model in 2D shown above should also exist in three dimensions (3D), though we cannot exactly solve 3D models. To see this, we have studied a 3D version of the 2D Kagome lattice which is a kind of body-centered lattice where the central spin in the lattice cell is free if the corner spins are in an antiferromagnetic order: the central spin has four up and four down neighbors making its energy zero as in the Kagome lattice. We have shown that the partial disorder exists [32,33] and the reentrant zone between phase F and phase X in Fig. 6 closes up giving rise to a line of first-order transition [34].

To close this paragraph, we note that for other exactly solved frustrated models, the reader is referred to the review by Diep and Giacomini [35].

3.2. Elementary excitations: surface magnons

We consider a thin film of NT layers with the Heisenberg quantum spin model. The Hamiltonian is written as

H = -2 E Ji^i- 2 £ DijSfSj

< ij >

-2 XJj(sfSZ + 2 (S+ST+ S-S+)) - 2 X DjSZS

<j V J <ij>

whereJj is positive (ferromagnetic) and Dij>0 denotes an exchange anisotropy. When Dij is very large with respect to Jij, the spins have an Ising-like behavior.

Fig. 7. Left: Magnetization of the sublattice 1 composed of cornered spins of ferromagnetic phase I (blue void squares) and the staggered magnetization defined for the phase IV of Fig. 2 (red filled squares) are shown in the reentrant region with a = J2/J1 = -0.94. See text for comments. Right: Susceptibility of sublattice 1 versus T.

For simplicity, let us suppose for the moment that all surface parameters are the same as the bulk ones with no defects and impurities. One of the microscopic mechanisms which govern thermodynamic properties of magnetic materials at low temperatures is the spin waves. The presence of a surface often causes spin-wave modes localized at and near the surface. These modes cause in turn a diminution of the surface magnetization and the magnetic transition temperature. The methods to calculate the spin-wave spectrum from simple to more complicated are (see examples given in Ref. [15]):

(i) the equation of motion written for spin operators S± of spin S occupying the lattice site i of a given layer. These operators are coupled to those of neighboring layers. Writing an equation of motion for each layer, one obtains a system of coupled equations. Performing the Fourier transform in the xy plane, one obtains the solution for the spin-wave spectrum.

(ii) the spin-wave theory using for example the Holstein-Primakoff spin operators for an expansion of the Hamilto-nian. This is the second-quantization method. The harmonic spin-wave spectrum and nonlinear corrections can be obtained by diagonalizing the matrix written for operators of all layers.

(iii) the Green's function method using a correlation function between two spin operators. From this function one can deduce various thermodynamic quantities such as layer magnetizations and susceptibilities. The advantage of this method is one can calculate properties up to rather high temperatures. However, with increasing temperature one looses the precision.

We summarize briefly here the principle of the Green's function method for illustration (see details in Ref. [36,37]). We define one Green's function for each layer, numbering the surface as the first layer. We write next the equation of motion for each of the Green's functions. We obtain a system of coupled equations. We linearize these equations to reduce higher-order Green's functions by using the Tyablikov decoupling scheme [38]. We are then ready to make the Fourier transforms for all Green's functions in the xy planes. We obtain a system of equations in the space ( kxy, u) where kxy is the wave vector parallel to the xy plane and u is the spin-wave frequency (pulsation). Solving this system we obtain the Green's functions and u as functions of k xy. Using the spectral theorem, we calculate the layer magnetization. Concretely, we define the following Green's function for two spins Si and Sj as

Gij(t, t') = (\S+(t); Sj-(t')yy (11)

The equation of motion of Gij(t, t') is written as dGij(t, t) ^-1,

(2ff)-^ [S+ (t),Sj- (t')]} + (( [S+;h] (t);Sj-(t')^^

where [...] is the boson commutator and (...) the thermal average in the canonical ensemble defined as

(f) = Tre-bH F/Tre-bH

with b = 1/kBT. The commutator of the right-hand side of Eq. (12) generates functions of higher orders. In a first approximation, we can reduce these functions with the help of the Tyablikov decoupling [38] as follows

SzmS+; ST)) = (Szm)((S+; S-)), (14)

We obtain then the same kind of Green's function defined in Eq. (11). As the system is translation invariant in the xy plane, we use the following Fourier transforms

Gjt, t' )=D ffdVxy 2P / du e-iu(t-t')

gn,n' (u, ~kxy) e^~Ri-R)

where u is the magnon pulsation (frequency), k xy the wave vector parallel to the surface, R i the position of the spin at the site i, n and n' are respectively the indices of the planes to which i and j belong (n = 1 is the index of the surface). The integration on k xy is performed within the first Brillouin zone in the xy plane. Let D be the surface of that zone. Eq. (12) becomes

(hu - An)gn,n' + Bn (1 - <5n,1)gn-1,n' + Cn (1 - 5n,Njgn+1,; = 25n.n' < Sz„ >

where the factors (1 - 5n1) and (1 - dn Nl) are added to ensure that there are no Cn and Bn terms for the first and the last layer. The coefficients An, Bn and Cn depend on the crystalline lattice of the film. We give here some examples:

• Film of simple cubic lattice

An = —2Jn < sn > Cgk + 2C(Jn + Dn)(Sn) + 2 Jn,n+1 + Dn,n+1) x {SSn+1) + ^Jn,n—1 + Dn ,n—1 ) iSn—1 )

Bn = 2Jn,n—1 < Sn > Cn = 2Jn;n+1 Sn

where C = 4 and gk = 2 [cos(kxa) + cos(kya)]. • Film of body-centered cubic lattice

An = 8(jn,n+1 + Dn,n+1) (S^+1) + 8 (Jn,n—1 + Dn,n—1 ^ (S^—1 )

Bn = 8Jn,n—1 < Sn > gk Cn = 8Jn,n+1 < Sn > gk

(18) (19)

(20) (21) (22)

where gk = cos(kxa/2)cos(kya/2)

Writing Eq. (16) for n = 1,2,...,NT, we obtain a system of NT equations which can be put in a matrix form

M(w)g = u

where u is a column matrix whose n-th element is 25„n < Sn >.

For a given k xy the magnon dispersion relation Zw( k xy) can be obtained by solving the secular equation det|M| = 0. There are NT eigenvalues Zw, (i = 1,...,Nj) for each kxy. It is obvious that w, depends on all (S^) contained in the coefficients An, Bn and Cn.

To calculate the thermal average of the magnetization of the layer n in the case where S = 1/2, we use the following relation (see chapter 6 of Ref. [15]):

1 - (S—S+ 2 \ nJn

where (Sn S+) is given by the following spectral theorem

/ \ 1 '

\|—S+ / = l/O D fl^xy j 2p [gn,n'(w + ie) — gn,n'(w — i'e)] dw _eikxr(Ri—Hj)^

ebw - 1

e being an infinitesimal positive constant. Eq. (24) becomes e/O D

= 1 — l/O D//d ^ / 2P [gn,n(w + ie)

— gn,n (w — ie)]

■bfeu_ 1

where the Green's function gn n is obtained by the solution of Eq.

gn;n =

|M|n |M|

|M|n is the determinant obtained by replacing the n-th column of | M| by u.

To simplify the notations we put Zw, = Ei and Zw = E in the following. By expressing

U(E — Ei)

we see that E, (i = 1,..., NT) are the poles of the Green's function. We can therefore rewrite gn n as

^fn(Ei)

A-^E —

where fn(E,-) is given by

fn(Ei) = :

|M|n(E,)

njsi(Ei — Ej)

Replacing Eq. (29) in Eq. (26) and making use of the following identity

x — -h x + -h we obtain

— = 2ffi5(x)

— D //dkxdky

fn(E,) ebb- 1

where n = 1,...,Nt.

As < Sn > depends on the magnetizations of the neighboring layers via E,(i = 1,...,NT), we should solve by iteration the Eq. (32) written for all layers, namely for n = 1,...,NT, to obtain the layer magnetizations at a given temperature j.

The critical temperature jc can be calculated in a self-consistent manner by iteration, letting all (Szn) tend to zero.

Let us show in Fig. 8 two examples of spin-wave spectrum, one without surface modes as in a simple cubic film and the other with surface localized modes as in body-centered cubic ferromagnetic case.

It is very important to note that acoustic surface localized spin waves lie below the bulk frequencies so that these low-lying energies will give larger integrands to the integral on the right-hand side of Eq. (32), making (Sn) to be smaller. The same effect explains the diminution of jc in thin films whenever low-lying surface spin waves exist in the spectrum.

Fig. 9 shows the results of the layer magnetizations for the first two layers in the films considered above with Nj = 4.

Calculations for antiferromagnetic thin films with collinear spin configurations can be performed using Green's functions [36]. The physics is similar with strong effects of localized surface spin waves and a non-uniform spin contractions near the surface at zero temperature due to quantum fluctuations [37].

3.3. Frustrated films

We showed above for a pedagogical purpose a detailed technique for using the Green's function method. In the case of frustrated thin films, the ground-state spin configurations are not only non collinear but also non uniform from the surface to the interior layers. In a class of helimagnets, the angle between neighboring spins is due to the competition between the NN and the NNN interactions. Bulk spin configurations of such helimagnets were discovered more than 50 years ago by Yoshimori [39] and Villain

Fig. 8. Left: Magnon spectrum E = hu of a ferromagnetic film with a simple cubic lattice versus k = kx = ky for NT=8 and D/J = 0.01. No surface mode is observed for this case. Right: Magnon spectrum E = hu of a ferromagnetic film with a body-centered cubic lattice versus k=kx = ky for NT = 8 and D/J = 0.01. The branches of surface modes are indicated by MS.

Fig. 9. Ferromagnetic films of simple cubic lattice (left) and body-centered cubic lattice (right): magnetizations of the surface layer (lower curve) and the second layer (upper curve), with Nt=4, D = 0.01J, J = 1.

[40]. Some works have been done to investigate the low-temperature spin-wave behaviors [41—43] and the phase transition [44] in the bulk crystals.

For surface effects in frustrated films, a number of our works have been recently done among which we can mention the case of a frustrated surface on a ferromagnetic substrate film [45], the fully frustrated antiferromagnetic face-centered cubic film [46], and very recently the helimagnetic thin films in zero field [47,48] and under an applied field [49].

The Green's function method for non collinear magnets has been developed for the bulk crystal [50]. We have extended this to the case of non collinear thin films in the works just mentioned. Since two spins S,- and Sj form an angle cos6y one can express the Hamiltonian in the local coordinates as follows [47]:

H = - X j1 (cos qij - 1^S+S+ + srSj-) +1 (cos 8ij + 1)

< ij > (

x (S+St + S-S+) + isin 6ij(s+ + S,-)S]

- 2sin eijSf{S+ + Sj-) + cos dySfSzl - X IijSZS cos 6V

' < i j >

< ij >

The last term is an anisotropy added to facilitate a numerical convergence for ultra thin films at long-wave lengths since it is known that in 2D there is no ordering for isotropic Heisenberg spins at finite temperatures [51].

The determination of the angles in the ground state can be done either by minimizing the interaction energy with respect to interaction parameters or by the so-called steepest descent method which has been proved to be very efficient [45,46]. Using their values, one can follow the different steps presented above for the collinear magnetic films, one then obtains a matrix which can be numerically diagonalized to get the spin-wave spectrum which is used in turn to calculate physical properties in the same manner as for the collinear case presented above.

Let us show the case of a helimagnetic film. In the bulk, the turn angle in one direction is determined by the ratio between the antiferromagnetic NNN interaction J2(<0) and the NN interaction J1. For the body-centered cubic lattice, one has cos 6 = -J1/ J2. The helimagnetic phase is stable for J2U > 1. Consider a film with the c axis perpendicular to the film surface. For simplicity, one supposes the turn angle along the c axis is due to J2. Because of the lack of neighbors, the spins on the surface and on the second layer have the turn angles strongly deviated from the bulk value [47]. The results calculated for various J2/J1 are shown in

C axis 0 1 2 3 4 5 6 7 8

Fig. 10. Left: Bulk helical structure along the c-axis, in the case a = 2p/3, namely J2/J1 = -2. Right: (color online) Cosinus of a1 = 61-62, ..., a7 = 67-68 across the film for J2/ J1 = -1.2,-1.4,-1.6,-1.8,-2 (from top) with Nz = 8: af stands for ei-ei+1 and X indicates the film layer i where the angle af with the layer (i+1) is shown. The values of the angles are given in Table 1: a strong rearrangement of spins near the surface is observed.

Table 1

Values of cos 6n,n+1 = an between two adjacent layers are shown for various values of J2/J^ Only angles of the first half of the 8-layer film are shown: other angles are, by symmetry, cos 678 = cos 612, cos 66 7 = cos 62,3, cos 65 6 = cos 63 4. The values in parentheses are angles in degrees. The last column shows the value of the angle in the bulk case (infinite thickness). For presentation, angles are shown with two digits.

J2/J cos q12 cos q23 cos q34 cos S4 5 a (bulk)

-1.2 0.985 (9.79°) 0.908(24.73°) 0.855 (31.15°) 0.843(32.54°) 33.56°

-1.4 0.955(l7.07°) 0.767 (39.92°) 0.716 (44.28°) 0.714(44.41°) 44.42°

-1.6 0.924(22.52°) 0.633 (50.73°) 0.624(51.38°) 0.625 (51.30°) 51.32°

-1.8 0.894(26.66°) 0.514(59.04°) 0.564(55.66°) 0.552(56.48°) 56.25°

-2.0 0.867(29.84°) 0.411 (65.76°) 0.525 (58.31°) 0.487(60.85°) 60°

Fig. 10 (right) for a film of Nz = 8 layers. The values obtained are shown in Table 1 where one sees that the angles near the surface (2nd and 3rd columns) are very different from that of the bulk (last column).

The spectrum at two temperatures is shown in Fig. 11 where the surface spin waves are indicated. The spin lengths at T = 0 of the different layers are shown in Fig. 12 as functions of J2/J1. When J2 tends to -1, the spin configuration becomes ferromagnetic, the spin has the full length 1/2.

The layer magnetizations are shown in Fig. 13 where one notices the crossovers between them at low T. This is due to the competition between quantum fluctuations, which depends on the strength of antiferromagnetic interaction, and the thermal fluctuations which depends on the local coordinations.

-2 -1.8 -1.6 -1.4 -1.2

Fig. 12. (Color online) Spin lengths of the first four layers at T = 0 for several values of P = J2/J1 with d = 0.1, Nz = 8. Black circles, void circles, black squares and void squares are for first, second, third and fourth layers, respectively. See text for comments.

Fig. 11. Spectrum E = hu versus k=kx = ky for J2/J1 = -1.4 at T = 0.1 (left) and T = 1.02 (right) for Nz = 8 and d = I/J1 = 0.1. The surface branches are indicated by s.

Fig. 13. (Color online) Layer magnetizations as functions of J for J2/J1 = —1.4 with d = 0.1, Nz = 8 (left). Zoom of the region at low J to show crossover (right). Black circles, blue void squares, magenta squares and red void circles are for first, second, third and fourth layers, respectively. See text.

3.4. Surface disordering and surface criticality: Monte Carlo simulations

As said earlier, Monte Carlo methods can be used in complicated systems where analytical methods cannot be efficiently used. Depending on the difficulty of the investigation, we should choose a suitable Monte Carlo technique. For a simple investigation to have a rough idea about physical properties of a given system, the standard Metropolis algorithm is sufficient [52,53]. It consists in calculating the energy E1 of a spin, then changing its state and calculating its new energy E2. If E2 < E1 then the new state is accepted. If E2 > E1 the new state is accepted with a probability proportional to exp[—(E2 — E1)/(kBJ)]. One has to consider all spins of the system, and repeat the "update" over and over again with a large number of times to get thermal equilibrium before calculating statistical thermal averages of physical quantities such as energy, specific heat, magnetization, susceptibility, ...

We need however more sophisticated methods if we wish to calculate critical exponents or to detect a first-order phase transition. For calculation of critical exponents, histogram techniques [54,55] are very precise: comparison with exact results shows an agreement often up to 3rd or 4th digit. To detect very weak firstorder transitions, the Wang-Landau technique [56] combined with the finite-size scaling theory [57] is very efficient. We have used this technique to put an end to a 20-year-old controversy on the nature of the phase transition in Heisenberg and XY frustrated stacked triangular antiferromagnets [58,59].

To illustrate the efficiency of Monte Carlo simulations, let us show in Fig. 14 the layer magnetizations of the classical counterpart of the body-centered cubic helimagnetic film shown in Section 3.3 (figure taken from Ref. [47]). Though the surface magnetization is

smaller than the magnetizations of interior layers, there is only a single phase transition.

To see a surface transition, let us take the case of a frustrated surface of antiferromagnetic triangular lattice coated on a ferromagnetic film of the same lattice structure [45]. The in-plane surface interaction is Js < 0 and interior interaction is J > 0. This film has been shown to have a surface spin reconstruction as displayed in Fig. 15.

We show an example where Js = —0.5J in Fig. 16. The left figure is from the Green's function method. As seen, the surface-layer magnetization is much smaller than the second-layer one. In addition there is a strong spin contraction at J = 0 for the surface layer. This is due to quantum fluctuations of the in-plane

Fig. 15. Non collinear surface spin configuration. Angles between spins on layer 1 are all equal (noted by a), while angles between vertical spins are b.

1.2 1. T

□ o □

Fig. 14. (Color online) Monte Carlo results: Layer magnetizations as functions of J for the surface interaction Js /J1 = 1 (left) and 0.3 (right) with J2/J1 = —2 and Nz = 16. Black circles, blue void squares, cyan squares and red void circles are for first, second, third and fourth layers, respectively.

0.15 0.1 0.05

0.2 0.4 0.6 0.

1.4 T 16

u Q r. n n X

0 0.2 0.4 0.6 0.8

1 1.2 1.4 1.6 1.8 7. 2

Fig. 16. Left: First two layer-magnetizations obtained by the Green's function technique vs. J for Js = —0.5J with anisotropies I = — ¡s = 0.1J. The surface-layer magnetization (lower curve) is much smaller than the second-layer one. Right: Magnetizations of layer 1 (circles) and layer 2 (diamonds) versus temperature J in unit of J/kB. See text for comments.

antiferromagnetic surface interaction Js. One sees that the surface becomes disordered at a temperature J1 =0.2557 while the second layer remains ordered up to J2 = 1.522. Therefore, the system is partially disordered for temperatures between J1 and J2. This result is very interesting because it confirms again the existence of the partial disorder in quantum spin systems observed earlier in the bulk [32,33]. Note that between J1 and J2, the ordering of the second layer acts as an external field on the first layer, inducing therefore a small value of its magnetization. Results of Monte Carlo simulations of the classical model are shown on the right of Fig. 16 which have the same features as the quantum case.

To close this paragraph we mention that the question of surface criticality has been a long-standing debate. On the one hand, pure theories would tell us that as long as the thickness is finite the correlation in this direction can be renormalized so that the nature of a phase transition in a thin film should be that of the corresponding 2D model. On the other hand, experimental observations and numerical simulations show deviations of critical exponents from 2D universality classes. The reader is referred to Refs. [60,61] for discussions on this subject.

3.5. Surface reorientation

In this paragraph, we would like to show the case of thin films where a transition from an in-plane spin configuration to a perpendicular spin configuration is possible at a finite temperature. Such a reorientation occurs when there is a competition between a dipolar interaction which tends to align the spins in the film surface and a perpendicular anisotropy which is known to exist when the film thickness is very small [10,11]. Experimentally, it has been observed in a thin Fe film deposited on a Cu(100) substrate that the perpendicular spin configuration at low temperatures undergoes a transition to a planar spin configuration as the temperature (J) is

increased [62—65]. Theoretically, this problem has been studied by many people [66—70]. Let us consider a 2D surface for simplicity. The case of a film with a small thickness has very similar results [70]. The Hamiltonian includes three parts: a 6-state Potts model Hp, a dipolar interaction Hd and a perpendicular anisotropy Ha:

Hp = —XJiJS(Si, Sj) (34)

where Si is a variable associated to the lattice site i. Si is equal to 1, 2, 3, 4, 5 and 6 if the spin at that site lies along the ±x, ±y and ±z axes, respectively. Jij is the exchange interaction between NN at i and j. We will assume that (i) Jj = Js if i and j are on the same film surface (ii) Jj = J otherwise.

Hd = DE(SS)3SM— 3 [S^-rijHS^-rij]| (35)

(-j) I rij rij J

where r,j is the vector of modulus r,j connecting the site i to the site j. One has rij=rj — r,-. S(s,) is a vector of modulus 1 pointing in the x direction if s, = 1, in the — x direction if s, = 2, etc. The perpendicular anisotropy is

Ha = — A Xsz(i)2 (36)

where A is a constant.

Using Monte Carlo simulations, we have established the phase diagram shown in Fig. 17 for two dipolar cutoff distances. Several remarks are in order: (i) in a small region above D = 0.1 (left figure) there is a transition from the in-plane to the perpendicular configuration when J increases from 0, (ii) this reorientation is a very strong first-order transition: the energy and magnetization are

1.16 1.12 1.08 1.04 1

(I) (II)

0.07 0.08 0.09 0.1 0.11

0.12 0.13 D

Fig. 17. (Color online) Phase diagram in 2D. Transition temperature TC versus D, with A = 0.5, J = 1, cutoff distance rc = 6 (left) and rc = 4 (right). Phase (I) is the perpendicular spin configuration, phase (II) the in-plane spin configuration and phase (P) the paramagnetic phase. See text for comments.

discontinuous (not shown) at the transition. Comparing to the Kagome Ising case shown in Fig. 6, we do not have a reentrant paramagnetic phase between phases I and II. Instead, we have a first-order transition as also observed near phase frontiers in other systems such as in a frustrated body-centered cubic lattice [34].

To conclude this subsection, we mention that competing interactions determine frontiers between phases of different symmetries. Near these frontiers, we have seen many interesting phenomena such as reentrance, disorder lines, reorientation transition, ... when the temperature increases.

between lattice spins H|, interaction between itinerant spins and lattice spins Hr, and interaction between itinerant spins Hm. We suppose

Hi = JijSiS (38)

where Si is the spin localized at lattice site i of Ising, XY or Heisenberg model, Jij the exchange integral between the spin pair Sj and S which is not limited to the interaction between nearest-neighbors (NN). For Hr we write

3.6. Spin transport in thin films

The total resistivity stem from different kinds of diffusion processes in a crystal. Each contribution has in general a different temperature dependence. Let us summarize the most important contributions to the total resistivity pt(T) at low temperatures in the following expression

pt (T)=po + A(T2 + A2T5 + A3ln m (37)

where Ai, A2 and A3 are constants. The first term is T-independent, the second term proportional to T2 represents the scattering of itinerant spins at low T by lattice spin-waves. Note that the resistivity caused by a Fermi liquid is also proportional to T2. The T5 term corresponds to a low-T resistivity in metals. This is due to the scattering of itinerant electrons by phonons. At high T, metals however show a linear-T dependence. The logarithm term is the resistivity due to the quantum Kondo effect caused by a magnetic impurity at very low T.

We are interested here in the spin resistivity p of magnetic materials. We have developed an algorithm which allows us to calculate the spin resistivity in various magnetically ordered systems [71—77], in particular in thin films. Unlike the charge conductivity, studies of spin transport have been regular but not intensive until recently. The situation changes when the electron spin begins to play a central role in spin electronics, in particular with the discovery of the colossal magnetoresistance [2,3].

The main mechanism which governs the spin transport is the interaction between itinerant electron spins and localized spins of the lattice ions (s-d model). The spin—spin correlation has been shown to be responsible for the behavior of the spin resistivity [80—82]. Calculations were mostly done by mean-field approximation (see references in [83]). Our works mentioned above were the first to use intensive Monte Carlo simulations for investigating the spin transport. We also used a combination of the Boltzmann equation [15,84] and numerical data obtained by simulations [73,74]. The Hamiltonian includes three main terms: interaction

Hr = -X h ai-Sj (39)

where si is the spin of the i-th itinerant electron and Ii; denotes the interaction which depends on the distance between electron i and spin Sj at lattice site j. For simplicity, we suppose the following interaction expression

Iij = ke-arij (40)

where rij = | ~ri - "rj |, I0 and a are constants. We use a cut-off distance D1 for the above interaction. Finally, for Hm, we use

Hm = -X j $Sj (41)

where Kij = K0e-br«(42)

with Ki,j being the interaction between electrons i and j. The system is under an electrical field which creates an electron current in one direction. In addition we include also a chemical potential which keeps electrons uniformly distributed in the system. Simulations have been carried out with the above Hamiltonian. The reader is referred to the original papers mentioned above for technical details. As expected, the spin resistivity reflects the spin—spin correlation of the system: p has the form of the magnetic susceptibility, namely it shows a peak at the phase transition. It is noted however that unlike the susceptibility which diverges at the transition, the spin resistivity is finite at Tc due to the fact that only short-range correlations can affect the resistivity (see arguments given in [81]). Moreover, it is known that near the phase transition the system is in the critical-slowing-down regime. Therefore, care should be taken while simulating in the transition region. This point has been considered in our simulations by introducing the relaxation time [78].

To illustrate the efficiency of Monte Carlo simulations, we show in Fig. 18 the excellent agreement of our simulation [79] and

Fig. 18. Left: Structure of MnTe of NiAs type. Antiparallel spins are shown by black and white circles. NN interaction is marked by Ji, NNN interaction by J2, and third NN one by J3. Right: p versus T. Black circles are from Monte Carlo simulation, white circles are experimental data taken from He et al. [85]. The parameters used in the simulation are taken from [86]: Ji = -21.5 K, J2 = 2.55 K, J3 = -9 K, Da = 0.12 K (anisotropy), Di = a = 4.148Ä and ¡0 = 2 K, e = 2*105 V/m.

experiments performed on MnTe [85]. The interactions and the crystalline parameters were taken from Ref. [86].

When a film has a surface phase transition at a low temperature in addition to the transition of the bulk at a higher temperature, one observes two peaks in the spin resistivity as shown in Ref. [73].

4. Conclusion

To conclude this review let us discuss on the relation between theories and experiments, in particular on the difficulties encountered when one is confronted, on the one hand, with simplified theoretical pictures and hypotheses and, on the other hand, with insufficient experimental knowledge of what is really inside the material. We would like to emphasize on the importance of a sufficient theoretical background to understand experimental data measured on systems which are more complicated, less perfect than models used to describe them. Real systems have always impurities, defects, disorder, domains,... However, as long as these imperfections are at extremely small amounts, they will not affect observed macroscopic quantities: theory tells us that each observable is a result from a statistical average over all microscopic states and over the space occupied by the material. Such an averaging will erase away rare events leaving only common characteristics of the system. Essential aspects can be thus understood from simple models if one includes correct ingredients based on physical arguments while constructing the model.

One of the striking points shown above is the fact that without sophisticated calculations, we cannot discover hidden secrets of the nature such as the existence of disorder lines with and without dimension reduction, the extremely narrow reentrant region between two ordered phases, the coexistence of order and disorder of a system at equilibrium etc. These effects are from the competition between various interactions which are unavoidable in real materials. These interactions determine the boundaries between various phases of different symmetries in the space of physical parameters. Crossing a boundary the system will change its symmetry. Theory tells us that if the symmetry of one phase is not a subgroup of the other then the transition should be of first order or the two phases should be separated by a narrow reentrant phase. Without such a knowledge, we may overlook such fine effects while examining experimental data.

We have used frustrated thin films to illustrate various effects due to a combination of frustration and surface magnetism. We have seen that to understand when and why surface magnetization is small with respect to the bulk one we have to go through a microscopic mechanism to recognize that low-lying localized surface spin-wave modes when integrated in the calculation of the magnetization will indeed mathematically lower its value. Common effects observed in thin films such as surface reconstruction and surface disordering can be theoretically explained.

We should emphasize on the importance of a combination of Monte Carlo simulation and theory. We have seen for example that we can determine the exact transition temperature in the Kagome model but the nature of the ordering is understood only with Monte Carlo simulation. This is not the only example: as theorists we need also hints and checks while constructing a theory, and as a simulator we need to understand what comes out from the computer since we often loose the track between inputs and outputs in a simulation. In this respect, a combination of numerical and theoretical methods is unavoidable.

Acknowledgments

I am grateful to my numerous former and present doctorate students with whom I shared uncountable wonderful moments of

scientific discussions and from whom I draw my source of energy and joy.

References

[1] H.T. Diep (Ed.), Frustrated Spin Systems, second ed., World Scientific, Singapore, 2013.

[2] M.N. Baibich, J.M. Broto, A. Fert, F. Nguyen Van Dau, F. Petroff, P. Etienne, G. Creuzet, A. Friederich, J. Chazelas, Phys. Rev. Lett. 61 (1988) 2472.

[3] P. Grunberg, R. Schreiber, Y. Pang, M.B. Brodsky, H. Sowers, Phys. Rev. Lett. 57 (1986) 2442. G. Binasch, P. Grunberg, F. Saurenbach, and W. Zinn, Phys. Rev. B 39(1989)4828.

[4] K.G. Wilson, Renormalization group and critical phenomena. I. Renormaliza-tion group and the Kadanoff scaling picture, Phys. Rev. B 4 (1971) 3174.

[5] D.J. Amit, Field Theory, Renormalization Group and Critical Phenomena, World Scientific, Singapore, 1984.

[6] J. Zinn-Justin, Quantum Field Theory and Critical Phenomena, Oxford Unver-sity Press, London, 2002.

[7] B. Berge, H.T. Diep, A. Ghazali, P. Lallemand, Phase transitions in two-dimensional uniformly frustrated XY spin systems, Phys. Rev. B 34 (1986) 3177.

[8] E.H. Boubcheur, H.T. Diep, Critical behavior of the two-dimensional fully frustrated XY model, Phys. Rev. B 58 (1998) 5163.

[9] Virgile Bocchetti, H.T. Diep, Monte Carlo simulation of melting and lattice relaxation of the (111) surface of silver, Surf. Sci. 614 (2013) 46.

[10] J.A.C. Bland, B. Heinrich (Eds.), Ultrathin Magnetic Structures, vol. I and II, Springer-Verlag, Berlin, 1994.

[11] A. Zangwill, Physics at Surfaces, Cambridge University Press, London, 1988.

[12] K. Binder, Critical hehaviour at surfaces, in: C. Domb, J.L Lebowitz (Eds.), Phase Transitions and Critical Phenomena, vol. 8, Academic Press, London, 1983.

[13] N.W. Ashcroft, N.D. Mermin, Solid State Physics, Saunders College, Philadelphia, 1976.

[14] P.M. Chaikin, T.C. Lubensky, Principles of Condensed Matter Physics, Cambridge University Press, 1995.

[15] H.T. Diep, Theory of Magnetism — Application to Surface Physics: Lectures, Problems and Solutions, World Scientific, Singapore, 2014.

[16] H.T. Diep, Statistical Physics: Fundamentals and Application to Condensed Matter, Lectures, Problems and Solutions, World Scientific, Singapore, 2015.

[17] R.J. Baxter, Exactly Solved Models in Statistical Mechanics, Academic Press, New York, 1982.

[18] E. Bayong, H.T. Diep, Effect of long-range interaction on the critical behavior of the continuous Ising model, Phys. Rev. B 59 (1999) 11919.

[19] E. Bayong, H.T. Diep, V. Dotsenko, Potts model with long-range interaction in one dimension Phys, Rev. Lett. 83 (1999) 14. Phys. Rev. Lett. 85(2000)5256.

[20] S. Reynal, H.T. Diep, Reexamination of the long-ranged Potts model: a mul-ticanonical approach, Phys. Rev. E 69 (2004) 026169.

[21] S. Reynal, H.T. Diep, Q-state Potts model with power-law decaying interactions: along the tricritical line, J. Appl. Phys. 95 (2004) 6968.

[22] L Onsager, Phys. Rev. 65 (1944) 117.

[23] P. Azaria, H.T. Diep, H. Giacomini, Coexistence of order and disorder and reentrance in an exactly solvable model, Phys. Rev. Lett. 59 (1987) 1629.

[24] M. Debauche, H.T. Diep, H. Giacomini, P. Azaria, Exact phase diagram in a generalized Kagom Ising lattice: reentrance and disorder lines, Phys. Rev. B 44 (1991) 2369.

[25] H.T. Diep, M. Debauche, H. Giacomini, Exact solution of an anisotropic centered honeycomb Ising lattice: reentrance and partial disorder, Phys. Rev. B (Rapid Commun.) 43 (1991) 8759.

[26] M. Debauche, H.T. Diep, Successive reentrances and phase transitions in exactly solved dilute centered square Ising lattices, Phys. Rev. B 46 (1992) 8214.

[27] P. Azaria, H.T. Diep, H. Giacomini, Ordering in the centered-square lattice Ising model, Phys. Rev. B 39 (1989) 740.

[28] H.T. Diep, M. Debauche, H. Giacomini, Reentrance and disorder solutions in exactly solvable Ising models, J. Mag. Mag. Mater 104—107 (1992) 184.

[29] K. Kano, S. Naya, Prog. Theor. Phys. 10 (1953) 158.

[30] A. Gaff, J. Hijmann, Phys. A 80 (1975) 149.

[31] J. Stephenson, J. Math. Phys. 11 (1970)420. Can. J. Phys. 48(1970)2118; Phys. Rev. B 1(1970)4405.

[32] R. Quartu, H.T. Diep, Partial order in frustrated quantum spin systems, Phys. Rev. B 55 (1997) 2975.

[33] C. Santamaria, H.T. Diep, Evidence of a partial disorder in a frustrated Heisenberg system, J. Appl. Phys. 81 (1997) 5276.

[34] P. Azaria, H.T. Diep, H. Giacomini, First order transition, multicriticality and reentrance in a BCC lattice with Ising spins, Europhys. Lett. 9 (1989) 755.

[35] H.T. Diep, Giacomini, Exactly solved frustrated models, in: H.T. Diep (Ed.), Frustrated Spin Systems, second ed., World Scientific, Singapore, 2013, pp. 1—58.

[36] The-Hung Diep, J.C.S. Levy, O. Nagai, Effect of surface spin-waves and surface anisotropy in magnetic thin films at finite temperatures, Phys. Stat. Solidi (b) 93 (1979) 351.

[37] H.T. Diep, Quantum effects in antiferromagnetic thin films, Phys. Rev. B 43 (1991) 8509.

[38] N. N. Bogolyubov and S. V. Tyablikov, Doklady Akad. Nauk S.S.S.R. 126 (1959) 53 [translation: Soviet Phys.-Doklady 4 (1959) 604].

[39] A. Yoshimori, J. Phys. Soc. Jpn. 14 (1959) 807.

[40] J. Villain, Phys. Chem. Solids 11 (1959) 303.

[41] I. Harada, K. Motizuki, J. Phys. Soc. Jpn. 32 (1972) 927.

[42] E. Rastelli, L. Reatto, A. Tassi, Quantum fluctuations in helimagnets, J. Phys. C 18 (1985) 353.

[43] H.T. Diep, Low-temperature properties of quantum Heisenberg helimagnets, Phys. Rev. B 40 (1989) 741.

[44] H.T. Diep, Magnetic transitions in helimagnets, Phys. Rev. B 39 (1989) 397.

[45] V. Thanh Ngo, H.T. Diep, Effects of frustrated surface in Heisenberg thin films, Phys. Rev. B 75 (2007), 035412, Selected for the Vir. J. Nan. Sci. Tech. 15(2007) 126.

[46] V. Thanh Ngo, H.T. Diep, Frustration effects in antiferrormagnetic face-centered cubic Heisenberg films, J. Phys. Condens. Matter 19 (2007) 386202.

[47] H.T. Diep, Quantum theory of helimagnetic thin films, Phys. Rev. B 91 (2015) 014436.

[48] Sahbi El Hog, H.T. Diep, Helimagnetic thin films: surface reconstruction, surface spin-waves, magnetization, J. Magn. Magn. Mater 400 (2016) 276—281.

[49] Sahbi El Hog and H. T. Diep, submitted for publication in Phys. Rev. B (March 2016).

[50] R. Quartu, H.T. Diep, Phase diagram of body-centered tetragonal Helimagnets, J. Magn. Magn. Mater 182 (1998) 38.

[51] N.D. Mermin, H. Wagner, Phys. Rev. Lett. 17 (1966) 1133.

[52] N. Metropolis, A.W. Rosenbluth, M.N. Rosenbluth, A.H. Teller, J. Chem. Phys. 21 (1953) 1087.

[53] K. Binder, D.W. Heermann, Monte Carlo Simulation in Statistical Physics, Springer-Verlag, Berlin, 1992.

[54] A.M. Ferrenberg, R.H. Swendsen, Phys. Rev. Let. 61 (1988) 2635. Phys. Rev. Let. 63(1989)1195.

[55] A.M. Ferrenberg, D.P. Landau, Phys. Rev. B 44 (1991) 5081.

[56] F. Wang, D.P. Landau, Phys. Rev. Lett. 86 (2001) 2050. Phys. Rev. E 64(2001) 056101.

[57] M.N. Barber, Finite-size scaling, in: C. Domb, J.L. Lebowitz (Eds.), Phase Transitions and Critical Phenomena, vol. 8, Academic Press, 1983, pp. 146—268.

[58] V.T. Ngo, H.T. Diep, Phase transition in Heisenberg stacked triangular anti-ferromagnets: end of a controversy, Phys. Rev. E 78 (2008) 031119.

[59] V.T. Ngo, H.T. Diep, Stacked triangular XY antiferromagnets: end of a controversial issue on the phase transition, J. Appl. Phys. 103 (2008), 07C712.

[60] X.T. Pham Phu, V. Thanh Ngo, H.T. Diep, Critical behavior of magnetic thin films, Surf. Sci. 603 (2009) 109—116 and references cited therein.

[61] X.T. Pham Phu, V. Thanh Ngo, H.T. Diep, Cross-over from first to second order transition in frustrated ising antiferromagnetic films, Phys. Rev. E 79 (2009) 061106.

[62] D.P. Pappas, K.P. Kamper, H. Hopster, Phys. Rev. Lett. 64 (1990) 3179—3182.

[63] R. Allenspach, A. Bischof, Phys. Rev. Lett. 69 (1992) 3385.

[64] C. Won, Y.Z. Wu, J. Choi, W. Kim, A. Scholl, A. Doran, T. Owens, J. Wu, X.F. Jin, H.W. Zhao, Z.Q. Qiu, Phys. Rev. B 71 (2005) 224429.

[65] A. Vaterlaus, C. Stamm, U. Maier, M.G. Pini, P. Politi, D. Pescia, Phys. Rev. Lett. 84 (2000) 2247.

[66] A. Hucht, A. Moschel, K.D. Usadel, J. Magn. Magn. Mater 148 (1995) 32.

[67] A. Hucht, K.D. Usadel, Phys. Rev. B 55 (1997) 12309.

[68] D. Pescia, V.L. Pokrovsky, Phys. Rev. Lett. 65 (1990) 2599—2601.

[69] C. Santamaria, H.T. Diep, J. Magn. Magn. Mater 212 (2000) 23.

[70] Danh-Tai Hoang, Maciej Kasperski, H. Puszkarski, H.T. Diep, J. Phys. Condens. Matter 25 (2013) 056006.

[71] K. Akabli, H.T. Diep, S. Reynal, Spin transport in magnetic multilayers, J. Phys. Condens. Matter 19 (2007) 356204.

[72] K. Akabli, H.T. Diep, Effects of ferromagnetic ordering and phase transition on the resistivity of spin current, J. Appl. Phys. 103 (2008), 07F307.

[73] K. Akabli, H.T. Diep, Temperature dependence of spin resistivity in ferromagnetic thin films, Phys. Rev. B 77 (2008) 165433.

[74] K. Akabli, Y. Magnin, M. Oko, I. Harada, H.T. Diep, Theory and Monte Carlo simulation of spin transport in antiferromagnetic films: application to MnTe, Phys. Rev. B 84 (2011) 024428.

[75] Danh-Tai Hoang, Y. Magnin, H.T. Diep, Spin resistivity in the frustrated J1-J2 model, Mod. Phys. Lett. B 25 (2011) 937.

[76] Y. Magnin, K. Akabli, H.T. Diep, I. Harada, Monte Carlo study of the spin transport in magnetic materials, Comput. Mater. Sci. 49 (2010) S204—S209.

[77] Y. Magnin, K. Akabli, H.T. Diep, Spin resistivity in frustrated antiferromagnets, Phys. Rev. B 83 (2011) 144406.

[78] Y. Magnin, Danh-Tai Hoang, H.T. Diep, Spin transport in magnetically ordered systems: effect of the lattice relaxation time, Mod. Phys. Lett. B 25 (2011) 1029.

[79] Y. Magnin, H.T. Diep, Monte Carlo study of the spin resistivity in semiconducting MnTe, Phys. Rev. B 85 (2012) 184413.

[80] P.-G. de Gennes, J. Friedel, J. Phys. Chem. Solids 4 (1958) 71.

[81] M.E. Fisher, J.S. Langer, Phys. Rev. Lett. 20 (1968) 665.

[82] T. Kasuya, Prog. Theor. Phys. 16 (1956) 58.

[83] M. Kataoka, Phys. Rev. B 63 (2001) 134435.

[84] C. Cercignani, The Boltzmann Equation and its Applications, Springer-Verlag, New York, 1988.

[85] X. He, Y.Q. Zhang, Z.D. Zhang, J. Mater. Sci. Technol. 27 (2011) 64.

[86] W. Szuszkiewicz, E. Dynowska, B. Witkowska, B. Hennion, Phys. Rev. B 73 (2006) 104403.