Scholarly article on topic ' Preparation of N-     TiO  2    Using a Microwave/Sol-Gel Method and Its Photocatalytic Activity for Bisphenol A under Visible-Light and Sunlight Irradiation '

Preparation of N- TiO 2 Using a Microwave/Sol-Gel Method and Its Photocatalytic Activity for Bisphenol A under Visible-Light and Sunlight Irradiation Academic research paper on "Chemical engineering"

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Academic research paper on topic " Preparation of N- TiO 2 Using a Microwave/Sol-Gel Method and Its Photocatalytic Activity for Bisphenol A under Visible-Light and Sunlight Irradiation "

Hindawi Publishing Corporation International Journal of Photoenergy Volume 2013, Article ID 439079, 9 pages http://dx.doi.org/10.1155/2013/439079

Research Article

Preparation of N-TiO2 Using a Microwave/Sol-Gel Method and Its Photocatalytic Activity for Bisphenol A under Visible-Light and Sunlight Irradiation

Chung-Hsin Wu,1 Chao-Yin Kuo,2 Chin-Jung Lin,3 and Peng-Ke Chiu2

1 Department of Chemical and Materials Engineering, National Kaohsiung University of Applied Sciences, 415 Chien-Kung Road, Kaohsiung 80778, Taiwan

2 Department of Safety Health and Environmental Engineering, National Yunlin University of Science and Technology, Yunlin 64002, Taiwan

3 Department of Environmental Engineering, National Ilan University, Ilan 26041, Taiwan Correspondence should be addressed to Chung-Hsin Wu; wuch@kuas.edu.tw Received 20 November 2012; Revised 4 January 2013; Accepted 13 January 2013 Academic Editor: Mahmoud M. El-Nahass

Copyright © 2013 Chung-Hsin Wu et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

This study applied the microwave/sol-gel method to prepare nitrogen-doped TiO2 (N-TiO2). The N-TiO2 was immobilized in glass balls to form N-TiO2/glass beads and applied to degrade Bisphenol A (BPA) under visible-light and sunlight irradiation. The characteristics of the prepared photocatalysts were analyzed by X-ray diffraction (XRD), UV-Vis spectroscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). Experimental results demonstrate that the percentage of anatase increased as the amount of N in N-TiO2 increased. Compared with the undoped TiO2 (420 nm), spectra show that the absorption edge shifted to a longer wavelength (445 nm) after N doping. The XPS characterization confirms the substitution of crystal lattice O to N species in N-TiO2, forming Ti-O-N and N-Ti-O. With an increased N/Ti ratio, photodegradation efficiency increased and then decreased; moreover, the optimal amount for N doping was determined as an N/Ti mole ratio of 0.08 (0.1 NT). The efficiency of 0.1 NT in doing BPA photodegradation was greater than that of Degussa P25. After reaction for 61min, the mineralization percentage of 0.1 NT under visible-light irradiation reached 41%. Photocatalyst efficiency decreased as the number of repeats increased in the visible-light/N-TiO2 system; however, these systems were stable during reaction.

1. Introduction

Bisphenol A (BPA), a monomer of various polymeric materials, is utilized primarily to produce epoxy resins and polycarbonate products [1]. Recent studies have shown that BPA can leach out of the plastic lining of food cans [2]. Due to its continued use in household and commercial products, large amounts of BPA have been released into aquatic environments. Based on its ability to disrupt endocrine function, the presence of BPA in aquatic environments and its potential adverse impacts on ecological and public health have garnered increased attention. Hence, researchers must develop effective remediation techniques that degrade BPA in wastewater.

Advanced oxidation processes (AOPs) are effective approaches for degrading and reducing recalcitrant wastewater loads from industrial processes. Significant progress has been made in developing AOPs for BPA degradation in recent years. Notably, AOPs involve primarily the generation of a very powerful nonselective oxidizing agent, the hydroxyl radical, which destroys pollutants. Because of its nontoxicity, photochemical stability, and reasonable cost, TiO2-based photocatalysis has been studied extensively for wastewater treatment. In ultraviolet light (UV)/TiO2-based systems, TiO2 particles absorb UV energy that is greater than the TiO2 band gap and form an electron and hole pair in the conduction band and valence band, respectively. The positive holes oxidize water molecules into hydroxyl

radicals, and negative electrons reduce molecular oxygen to yield superoxide radical anions. These positive holes, hydroxyl radicals, and superoxide radical anions are the dominant oxidizing species in UV/TiO2 systems. However, rapid unfavorable recombination of photo-produced electrons and holes in TiO2 markedly reduces the photocatalytic efficiency. Additionally, TiO2 can only be photoexcited by UV; hence, developing photocatalysts that make full use of solar energy is necessary. Several investigations have synthesized sulfur-doped TiO2 (S-TiO2) [3, 4] and nitrogen-doped TiO2 (N-TiO2) [5-7], which extend the spectral response of TiO2 into the visible light region, thereby enhancing the photocatalytic activity of TiO2.

Various studies have used different AOPs to treat BPA, including ozone [8, 9], UV/ozone [8], UV/TiO2 [10-14], visible-light/TiO2 [15-17], sunlight/TiO2 [18], UV/Zr-TiO2 [19], UV/Pt-TiO2 [12], UV/Au-TiO2 [13], Fenton [14, 20, 21], UV/Fenton [20], ultrasound (US) [22, 23], US/Fenton [21], US/TiO2/Fe2+ [14], visible-light/N-TiO2 [17], and visible-light/C-N-TiO2 [24,25] systems. Notably, BPA can be readily eliminated by the US process (~90 min); however, over 80% of the total organic carbon (TOC) remained in the solution after US irradiation for 9h [23]. Additionally, the US/Fenton system increased the BPA degradation rate as compared to the Fenton system only [21]. The Zr-doped [19], Au-doped [13], and Pt-doped [12] TiO2 photocatalysts had better photocatalytic efficiency than pure TiO2 during the degradation of BPA under UV irradiation. Wang and Lim [24], who applied visible-light to photoexcite N-TiO2 and Degussa P25 for BPA degradation, demonstrated that the BPA removal percentage after reaction for 2 h was 29% and 5%, respectively. The BPA photodegradation rate under visible-light irradiation was as follows: N-TiO2 > Degussa P25 > undoped TiO2 [17]. Since Sojic et al. [26] suggested that nonmetals are more efficient dopants than metals for TiO2, TiO2 and N-TiO2 were selected as photocatalysts for BPA degradation in this study.

A slurry reactor system was used in most experiments, in which TiO2 particles were suspended in the form of a colloid and utilized as a photocatalyst. However, the required separation of the ultrafine photocatalyst particles from the treated liquid hindered the wide application of slurry photocatalytic reaction systems. Only Nakashima et al. [10] and Wang et al. [15] have used a UV/immobilized TiO2 system to degrade BPA. No study has investigated the BPA photodegradation by visible-light/immobilized TiO2 and sunlight/immobilized TiO2 systems. This study synthesizes TiO2 and N-TiO2 using the microwave/sol-gel method and immobilizes photocatalysts on glass balls to form fixed beads. The objectives of this study are to (i) identify the characteristics of prepared TiO2 and N-TiO2 particles, (ii) compare the photocatalytic activity of TiO2 and N-TiO2 for BPA degradation under visible-light and sunlight irradiation under an immobilized condition, (iii) determine the effects of photocatalyst dosage and amount of N doping, and (iv) investigate repeated usability of the visible-light/immobilized N-TiO2 system for BPA degradation.

60 mL C2H5 OH

180 mL D.I. water

Urea (0.3, 0.5, 1, 3, and 9 g)

8 mL HNO3

250 rpm stirring for 24 h

Heating at 120° C for 12 h

5 mL D.I. water

700 W microwave irradiation for 30 min

N-TiO2

D.I. wate washing

5 mL D.I. water Glass balls

Heating at 120°C for 12 h

N-TiO2/glass bead

Figure 1: Flowchart for the procedure used to prepare immobilized N-TiO2/glass bead.

2. Materials and Methods

2.1. Materials. The Ti and N source was ethyl titanate (C8H20O4Ti) and urea, respectively (Merck). Ethanol was applied as a modulator when preparing TiO2. The parent compound, BPA, was obtained from Sigma-Aldrich (purity > 99%). Solution pH was adjusted using HNO3 and NaOH. Degussa P25 was utilized as the standard material to compare photocatalytic activity of prepared TiO2 and N-TiO2 for BPA photodegradation. All chemicals were analytical reagent grade and used as received.

2.2. Preparation of the Immobilized TiO2/Glass Bead and N-TiO2/Glass Bead. Figure 1 presents a flowchart of the procedure used to prepare immobilized N-TiO2/glass beads. In preparing N-TiO2, 44 mL C8H20O4Ti was mixed with 60 mL ethanol and then mixed further with 180 mL deionized water. An appropriate amount of urea (0.3, 0.5,1, 3, and 9 g) was added. Then, 8 mL HNO3 was added, and the entire mixture was stirred at 250 rpm for 24 h. After gel formation, the batch was dehydrated at 120° C. Dehydrated gels were first ground, and 5 mL deionized water was then added. The resulting gels were irradiated in a 700 W microwave (24252475 MHz) for 30 min to generate N-TiO2 powder. Glass balls (5 mm in diameter) were etched to generate a rugged surface

44 mL C8 H20O4Ti

in 5 M NaOH (100°C) for 5 h. The N-TiO2 and pretreated glass balls were washed 5 times with deionized water. The clean and etched glass balls were immersed in a 5% (w/v) N-TiO2 solution. The glass balls were conditioned at 120°C for 12 h to form immobilized N-TiO2/glass beads. The mole ratio of N/Ti for the obtained N-TiO2/glass beads under addition of 0.3, 0.5, 1, 3, and 9 g urea was 0.05, 0.08, 0.17,

0.5, and 1.5, respectively, and these N-TiO2/glass beads are denoted as 0.05 NT, 0.1 NT, 0.2 NT, 0.5 NT, and 1.5 NT herein, respectively. If no urea was added, the TiO2/glass beads (T) were produced. The 5% (w/v) Degussa P25 solution was also calcined with pretreated glass balls at 120° C for 12 h to form a Degussa P25/glass beads (P).

2.3. Characterization. The crystallinity of photocatalysts was analyzed by X-ray diffraction (XRD) using CuKa radiation (Bruker AXS). Accelerating voltage and applied current were 40 kV and 30 mA, respectively. The XRD patterns were recorded as 20 values at 10-80° and a scanning speed of 3°/min. The UV-Vis spectroscopy (Jasco V-670) method was applied to profile the absorbance spectrum of photocatalysts at wavelengths of200-800 nm. The UV-Vis diffuse reflectance spectra were used to calculate photocatalyst band gap energy. Functional groups of photocatalysts were identified by Fourier transform infrared spectroscopy (FTIR) using a Spectrum One and AutolMAGE system (Perkin Elmer) via theKBr presseddiscmethod. An inductivelycoupled plasma-optical emission spectrometer (ICP-OES, Optima 2100DV) was utilized to measure the TiO2 concentration in effluent. The X-ray photoelectron spectroscopy (XPS) measurements were performed using a Vacuum Generator ESCALAB MKn photoelectron spectrometer (East Grinsted) with an ALKR

1, 2 (1486.6 eV) X-ray source. Binding energies of photoelec-trons were determined based on the assumption that carbon 1s electrons were at 284.5 eV. The BPA concentration was measured using a high-performance liquid chromatograph (HPLC) with a UV detector (Agilent Technologies). The UV detector was set to a wavelength of 197 nm. Separations were performed using a Supelcosil C18 column (Supelco). The mobile phase was Milli-Q water and CH3CN (40: 60 v/v) at a flow rate of 0.5mL/min. Injection volume was 20 ^L. The decrease in TOC, measured using an O.I. 1010 TOC analyzer, indicated a BPA mineralization.

2.4. Photodegradation of BPA. The photocatalytic reactor (Figure 2) consisted of 4 30 cm long quartz tubes and 5 visible-light lamps. The external diameter of each tube was 1.2 cm, and the internal diameter was 1 cm. In total, 10-40 photocatalyst/glass balls were filled into each quartz tube before 10mg/L of BPA solution was introduced into the system using a peristaltic pump. The photocatalyst dosage in the photocatalytic reactor was 1.7-6.7 g/L. The optimal experimental pH for BPA degradation in the sunlight/TiO2 system was 6, because a chemical treatment was not needed, including a neutralization process [18]. Hence, the initial solution pH was adjusted to 6 herein. The flow rate of the BPA solution was maintained at 1.5mL/min. The column photoreactor was irradiated with 410 nm visible light (8W,

/K----

Figure 2: The scheme of the column photoreactor ((1) storage tank, (2) peristaltic pump, (3) light source, (4) column, (5) samplingpores, and (6) connection tube).

0.5 NT

0.1 NT

0.05 NT

10 20 30 40 50 60 70 80 20

Figure 3: XRD pattern of photocatalysts.

Philips) at room temperature. The quartz tubes were arranged at equal distances around the 5 lamps. Moreover, the system was analyzed under sunlight in selected experiments for comparison purposes. The intensity of visible light and sunlight was 2.88 and 23.46-24.06 mW/cm2, respectively. Some experiments were performed in triplicate, and average values are reported.

3. Results and Discussion

3.1. Physical Characterization of Photocatalysts. Figure 3 shows XRD patterns of N-TiO2 samples with differing N content. The 20 peaks at 25.5°, 37.8°, and 48.1° indicate anatase-type TiO2, and those at 27.5° and 36.1° indicate rutile-type TiO2. No N-derived peak was detected in any pattern. Anatase is considered the photoactive form, whereas rutile exhibits low photocatalytic activity. However, the source of the activity difference remains unknown. The ratio of anatase to rutile in photocatalysts was calculated using the following well-known formula [27]:

XA (%) =

IA + 1.265IR

x 100,

Table 1: Characteristics of the prepared photocatalysts.

Photocatalysts

Crystalline phase Anatase (%) Rutile (%)

Absorbed wavelength (nm)

Band gap (eV)

0.05 NT 0.1 NT 0.2 NT 0.5 NT 1.5 NT

82.1 38.7 33.2

34.5 41.9 63.0

61.3 66.8 65.5 58.1 37.0

413 420 429 438 445 445 445

3.00 2.95 2.89 2.83 2.79 2.79 2.79

0 500 1000 1500 2000 2500 3000 3500 4000 4500 Wavenumber (cm-1)

0.05 NT 0.1 NT

0.2 NT 0.5 NT 1.5 NT

Figure 4: FTIR spectra of different photocatalysts.

where XA is the fraction of anatase in the photocatalyst, IA is the (101) peak intensity of anatase at 25.5°, IR is the (110) peak intensity of rutile at 27.5°, and 1.265 is the scattering coefficient. Degussa P25, which is a standard material in photocatalytic reactions, contains anatase and rutile phases at aratio ofroughly3:1 (Table 1). The synthesized TiO2 particles have less anatase than Degussa P25. As the amount of N in N-TiO2 increases, the ratio of anatase to rutile increases (Table 1). The XRD diagrams indicate that N doping retards the transformation of TiO2 phase from anatase to rutile. This retardation of phase transformation may be due to stabilization of the anatase phase by surrounding N ions via the formation ofTi-O-N bonds. Ma etal. [7] obtained similar analytical results for samarium doping.

The electronic structure of a photocatalyst affects its optical absorption and migration of light-induced electrons and holes. The band gap of the photocatalyst was calculated using the formula Eg = 1240/A^, where Xg is the wavelength value corresponding to the intersection point of the vertical and horizontal section of spectra. The impact of N doping on the band gap of N-TiO2 is investigated (Table 1). Compared with undoped TiO2 (420 nm), the spectra show the absorption edge shifting to a longer wavelength (445 nm) after N doping. All N-TiO2 had high photoabsorption capacity in the range of UV light to visible light, and the number of photo-generated electrons and holes to participate in

the photocatalytic reaction was increased; additionally, the significant narrowing of the band gap is of great importance for practical applications of N-TiO2 since N-TiO2 can be activated by sunlight (Table 1).

The band gap energy of Degussa P25 was 3.00 eV (Table 1), and this value was the same as that determined by Silveyra et al. [6] and Liu et al. [28]. The band gap energy of TiO2 decreased from 2.95 eV to 2.79 eV via N doping (Table 1). In previous studies, the band gap energy of TiO2 decreased from 3.01 eV to 2.88 eV via N doping [6]; moreover, the same trend (band gap energy of TiO2 decreasing from 3.09 eV to 2.84 eV) was also obtained by Ma et al. [7]. Hussain et al. [29] and Wang et al. [30] indicated that the band gap value of a photocatalyst decreases as the amount of dopant increases. Notably, N-doping was effective in decreasing the band gap of TiO2 by generating an isolated N 2p narrow band above the O 2p valence, which formed by incorporating N atoms into the TiO2 lattice [5].

Figure 4 shows the FTIR spectra of different photocatalysts obtained with different urea concentrations. Three major absorbance peaks were observed at 1384,1625, and 3130 cm-1. The absorption peak at 1625 cm-1 belongs to the Ti-O structure [29, 31, 32]. The board absorption band at 31003300 cm-1 was characteristic of OH- stretching vibrations on the photocatalyst surface [31]. The peak at 1384 cm-corresponds to the surface adsorbed NO3- molecules [33]. Adsorption of NO3- molecules onto prepared photocatalysts can be attributed to adding HNO3 during photocatalyst preparation. Hu et al. [34] demonstrated that hydrolysis of TiCl4 in a urea solution led to chemisorption of NH3 molecules on the TiO2 surface and to the formation of nitride species in the TiO2 lattice. However, N atoms incorporated into the TiO2 crystal lattice were not identified by FTIR analysis in this study.

The XPS characterization further confirms the substitution of crystal lattice O for N species in N-TiO2. Figure 5 shows XPS spectra for the N 1s region of N-doped TiO2 for 0.05 NT, 0.1 NT, 0.2 NT, and 0.5 NT, respectively, and their fitting curves. After curve fitting, two peaks with binding energies of 399 and 401 eV were identified. The peak at 399 eV has been attributed to anionic N in N-Ti-O linkages by many researchers [5, 35]. Another peak at a higher binding energy of 401 eV for the N 1s region of N-TiO2 was attributed to oxidized N in Ti-O-N. Xing et al. [36] indicated that this oxidized N in Ti-O-N is chemically adsorbed onto the

394 396 398 400 402 404 406 394 396 398 400 402 404 406 Binding energy (eV) Binding energy (eV)

(a) (b)

(c) (d)

Figure 5: Fitting XPS spectra for N 1s region of N-doped TiO2 for (a) 0.05 NT, (b) 0.1 NT, (c) 0.2 NT, and (d) 0.5 NT.

catalyst surface and appears at a high binding energy of 401 eV in N 1s XPS spectra. The Ti 2p region of 0.2 NT shows that the Ti2p3/2 and Ti2p1/2 core levels in N-TiO2 appear at 458.5 and 464.3 eV, respectively (Figure 6). The binding energies of Ti 2p3/2 and Ti 2p1/2 after N doping decreased when compared with that of pure TiO2 (Ti 2p3/2 appears at 459.1 eV, and Ti 2p1/2 appears at 465.0 eV). The possible reason is that N is incorporated into the lattice and substitutes for O, and the lower electronegativity of N compared with that of O leads to electron transformation from N to Ti to increase electron density on Ti [31, 37]. The XPS spectra of the O 1s region of 0.2 NT have two peaks after curve fitting (Figure 7). The peak at 529.8 eV is attributed to O 1s in Ti-O linkages of TiO2. Another peak at 531.5 eV is attributed to the presence of Ti-O-N bonds [38, 39]. The peaks at about 529.8 and 531.5 eV indicate the presence of two oxygen states, Ti-O-Ti and Ti-O-N, respectively. Based on these observations, we conclude that the chemical states of N-doped TiO2 may coexist as N-Ti-O (N1) and Ti-O-N (N2). According to the XPS spectra, different fitting peak nitrogen percentages in the

Table 2: Nitrogen doping ratio of 0.05 NT, 0.1 NT, 0.2 NT, and 0.5 NT.

0.05 NT 0.1 NT 0.2 NT 0.5 NT

N1/Ti 0.00200 0.00249 0.00546 0.00384

N2/Ti 0.00053 0.00007 0.00009 0.00196

N1/N2 3.8 35.5 63.5 2.0

Total doping N 0.15% 0.16% 0.33% 0.35%

N1 refers to N in N-Ti-O linkages. N2 refers to N in Ti-O-N.

TiO2 were calculated in relation to titanium (Table 2). The highest N1/N2 ratio was 0.2 NT; additionally, the highest N-doping concentration was 0.5 NT (Table 2). Xing et al. [36] indicated that when the N/Ti value increases, the ratio of N1/N2 increases first and then decreases; this study obtained a similar trend.

3.2. Effects of Photocatalyst Dosage and Amount ofN Doping in TiO2. Under the addition of 6.7 g/L photocatalyst, the adsorption of BPA by T, P, 0.05 NT, 0.1 NT, 0.2 NT, 0.5 NT,

456 458 460 462 464 466 Binding energy (eV)

Figure 6: XPS spectra for Ti 2p region of 0.2 NT.

526 528 530 532 534 Binding energy (eV)

Figure 7: XPS spectra for O 1s region of 0.2 NT.

and 1.5 NT after reaction for 61min was 25%, 5%, 15%, 12%, 10%, 11%, and 12%, respectively. After reaction for 61min, the photolysis of BPA by 410 nm visible light, and sunlight irradiation was 4% and 29%, respectively. The BPA removal was ineffective by photocatalyst adsorption and photolysis. Figure 8 shows the BPA removal percentages under different photocatalyst dosages. Under 410 nm visible-light irradiation on 0.2 NT, BPA removal at 1.7, 3.3, 5.0, and 6.7 g/L was 29%, 49%, 59%, and 64%, respectively; additionally, for 0.2 NT under sunlight irradiation, BPA removal was 49%, 60%, 74%, and 75%, respectively. The BPA degradation efficiency increased as the amount of photocatalyst increased. This increase in efficiency is due to an increased total surface area, namely, the number of active sites, available for the photocatalytic reaction as the photocatalyst dosage increased [18]. Under the same photocatalyst dose, BPA removal percentage for 0.2 NT was higher than that for T and P. This study demonstrates that photocatalytic activity of TiO2 was enhanced by N doping.

Figure 9 shows the effects of the N doping dosage in TiO2 for BPA removal. Under 410 nm visible-light irradiation, BPA

T (410 nm) P (410 nm)

Photocatalyst dosage (g/L)

В 0.2 NT (410 nm) □ 0.2 NT (sunlight)

Figure 8: BPA removal percentage at different photocatalyst dosages (BPA = 10 mg/L, pH = 6, and time = 61 min).

0.05 NT 0.1 NT 0.2 NT 0.5 NT 1.5 NT Photocatalysts

■ 410 nm

■ Sunlight

Figure 9: BPA removal percentage at different N-TiO2 (BPA 10 mg/L, pH = 6, time = 61 min, and photocatalyst = 6.7 g/L).

removal of 0.05 NT, 0.1 NT, 0.2 NT, 0.5 NT, and 1.5 NT was 66%, 68%, 64%, 62%, and 56%, respectively; moreover, under sunlight irradiation, BPA removal was 84%, 91%, 75%, 88%, and 53%, respectively. With the increase in the N/Ti ratio (ratio of urea to TiO2), photodegradation efficiency first increases and then decreases (Figure 9). The effects of the N doping dosage in catalyst for photodegradation efficiency were similar to those observed by Xing et al. [36]. A high doping concentration of N increases the energy shift due to a significant overlap of N and O states, leading to a narrowband gap in N-TiO2 (Table 1). An optimal amount of C, N, and/or S dopant exists at which they can synergistically serve as electron traps that inhibit recombination of photogenerated electron-hole pairs [5, 40]. However, an excessive amount of dopant can act as charge recombination centers. The optimal N doping amount in TiO2 in this study was identified as the N/Ti mole ratio of 0.08 (0.1 NT).

3.3. Comparisons of Different Photocatalysts for BPA Degradation. Figures 10 and 11 show the effects of different photo-catalysts on BPA removal rate under 410 nm visible-light and sunlight irradiation, respectively. The BPA photodegradation rate satisfies pseudo-first-order kinetics, and various studies

30 40 Time (min)

-a- 0.1 NT

—x— Direct photolysis

Figure 10: Photodegradation of BPA under 410 nm visible-light irradiation (BPA = 10 mg/L, pH = 6, and photocatalyst = 6.7 g/L).

30 40 Time (min)

-a- 0.1 NT

—x— Direct photolysis

Figure 11: Photodegradation of BPA under sunlight irradiation (BPA = 10 mg/L, pH = 6, and photocatalyst = 6.7 g/L).

Table 3: The pseudo-first-order rate constants of BPA for different photocatalysts (BPA = 10 mg/L, pH = 6, and photocatalyst = 6.7 g/L).

410 nm visible light Sunlight

к (hr-1) R2 к (hr-1) R2

P 0.90 0.986 1.60 0.976

T 0.68 0.986 1.12 0.943

0.05 NT 1.13 0.948 1.89 0.960

0.1 NT 1.21 0.922 2.59 0.961

0.2 NT 1.06 0.993 1.43 0.929

0.5 NT 0.89 0.982 2.00 0.977

1.5 NT 0.73 0.983 0.83 0.936

and sunlight irradiation. Therefore, 0.1 NT was utilized to evaluate BPA mineralization. The BPA removal percentage for P and 0.1 NT was 58% and 68%, respectively; additionally, the TOC removal percentage for P and 0.1 NT was 4% and 41%, respectively. Experimental results indicate that 0.1 NT was the best photocatalyst for BPA and TOC degradation.

Figure 12 lists the photocatalytic efficiency of repeated tests for P and 0.1 NT under 410 nm visible-light irradiation. The BPA removal of P in runs 1, 2, 3, 4, and 5 was 60%, 58%, 50%, 42%, and 39%, respectively; moreover, that of 0.1 NT was 68%, 66%, 59%, 52%, and 49%, respectively. Photocatalyst efficiency decreased as the number of repeats increased. The factor of (efficiency in run 5)/(efficiency in run 1) for P and 0.1 NT was 0.65 and 0.72, respectively. The performance of cyclic usability for 0.1 NT was greater than that for P. The concentration of released TiO2 in effluent for 0.1 NT was 1.13 mg/L in run 1; additionally, no TiO2 was released in effluent during runs 2-5. Experimental results demonstrate that 0.1 NT was the best photocatalyst, and visible-light-immobilized N-TiO2 and sunlight-immobilized N-TiO2 systems are suitable for BPA degradation. Additionally, visible-light-immobilized N-TiO2 system was stable during photocatalytic degradation.

have demonstrated that photodegradation rates for organics can be approximated using pseudo-first-order kinetics [7,16, 17]. The BPA photodegradation rate was 0.1 NT > P > T > photolysis for 410 nm visible-light and sunlight irradiation. The BPA photodegradation rate by sunlight irradiation was higher than that by 410 nm visible-light irradiation because the intensity of sunlight is greater than that of 410 nm visible light. Table 3 lists the pseudo-first-order rate constants (k) of BPA for different photocatalysts. Under 410 nm visible-light irradiation, k values were in the order of 0.1 NT > 0.05 NT > 0.2 NT > P > 0.5 NT > 1.5 NT > T. Photocatalytic activity was improved significantly by N doping. Yang et al. [17] demonstrated that BPA removal percentage of undoped TiO2, Degussa P25, and N-TiO2 under visible-light irradiation in a suspended system was 5%, 15%, and 30%, respectively, and the trend was similar to that in this study. Obviously, 0.1 NT had the fastest photodegradation rate and the highest removal percentage for BPA under both 410 nm visible-light

4. Conclusions

This investigation utilized N-TiO2/glass immobilized beads to degrade BPA. The ratio of anatase in prepared N-TiO2 increased as the N/Ti ratio increased; conversely, band gap energy decreased as the N/Ti ratio increased. Two forms of N-TiO2, Ti-O-N and N-Ti-O, were identified by XPS analysis. The optimal N/Ti mole ratio was 0.08, and N doping synergistically served as electron traps that inhibited recombination of photogenerated electron-hole pairs. The BPA degradation efficiency increased as the photocatalyst dose increased; moreover, the photocatalytic activity of N-TiO2 was higher under sunlight irradiation than under visible-light irradiation. The TOC removal percentage during BPA photodegradation was 0.1 NT > P. This study suggested that visible-light-immobilized N-TiO2 and sunlight-immobilized N-TiO2 systems are effective for BPA degradation. Moreover, the visible-light-immobilized N-TiO2 system had a high cyclic efficacy for BPA photodegradation.

30 20 10 0

0 61 122 183 244 305

Time (min)

Figure 12: Photocatalytic efficiency of cyclic tests for (a) P and (b) 0. 6.7 g/L).

20 -10 -0

0 61 122 183 244 305

Time (min)

—♦— Run 1 -х- Run 4

-♦- Run 2 -в- Run 5

-är- Run 3

(BPA = 10 mg/L, pH = 6, 410 nm visible light, and photocatalyst =

Acknowledgment

The authors would like to thank the National Science Council

Taiwan, for financially supporting this research under Contract no. NSC 101-2221-E-151-038-MY3.

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